2-硝基苯基2,3,4,6-四-O-乙酰基-alpha-D-吡喃葡萄糖苷合成路线 (共 2 条)
参考文献
Montgomery et al.
Journal of the American Chemical Society, 1942 , vol. 64, p. 690,693
Journal of the American Chemical Society, 1943 , vol. 65, p. 3,6
反应条件
1: o-hydroxynitrobenzene With 1-n-butyl-3-methylimidazolium chloride; silver(l) oxide T=25°C; Koenigs-Knorr type coupling; 0.25 h; Darknessneat (no solvent); 2: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide T=25 - 80°C; Koenigs-Knorr type coupling; 0.5 h; Darknessneat (no solvent); optical yield given as percent destereoselective reaction;
参考文献
Kumar, Vineet; Talisman, Ian Jamie; Malhotra, Sanjay V.
European Journal of Organic Chemistry, 2010 , # 18 p. 3377 - 3381