1: With chloro-trimethyl-silane; magnesium in tetrahydrofuran T=-5 - 20°C; 0.5 h; 2: With hydrogen bromide in tetrahydrofuran; water Product distribution / selectivity;
1: With chloro-trimethyl-silane; magnesium in tetrahydrofuran T=-5 - 20°C; 0.5 h; 2: With hydrogen bromide in tetrahydrofuran; water Product distribution / selectivity;
isopropanol-OD; sodium isopropanolate T=65°C; 50 h; regiospecificity of the hydrogen exchange; other substrate, other base, other deuterated alcohol, other temperature and time;
参考文献
Chung, Sung-Kee; Sasamoto, Kazumi
Journal of Organic Chemistry, 1981 , vol. 46, # 22 p. 4590 - 4592
