3-苯基-1-丙基硼酸频哪酯合成路线 （共 24 条）
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tripotassium phosphate monohydrate; P(t-Bu)2Me*HBF4 in water; tert-butyl alcohol T=60°C; Inert atmosphere;
参考文献
Joshi-Pangu, Amruta; Ma, Xinghua; Diane, Mohamed; Iqbal, Sidra; Kribs, Robert J.; Huang, Richard; Wang, Chao-Yuan; Biscoe, Mark R.
Journal of Organic Chemistry, 2012 , vol. 77, # 15 p. 6629 - 6633
反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With potassium ethanolate in i-Pr2O T=20°C; Miyaura borylation; 1 h; Inert atmosphere; 2: (3-iodoprop-1-yl)benzene With (R,R)-Pri-Pybox; [(diglyme)NiBr2] in i-Pr2O; dimethylammonium 2,4-dichlorophenoxyacetate T=20°C; Miyaura borylation; 3 h; Inert atmosphere;
参考文献
Dudnik, Alexander S.; Fu, Gregory C.
Journal of the American Chemical Society, 2012 , vol. 134, # 25 p. 10693 - 10697
反应条件
terpyridine; [RhCl(η2:η2-cycloocta-1,5-diene)]2; sodium t-butanolate T=80°C; 24 h; Inert atmosphere; Reagent/catalystSolventTemperature;
参考文献
Gong, Tian-Jun; Jiang, Yuan-Ye; Fu, Yao
Chinese Chemical Letters, 2014 , vol. 25, # 3 p. 397 - 400
反应条件
1: With 6-di-tert-butylphosphinomethyl-2,2'-bipyridine in tetrahydrofuran 0.0166667 h; Inert atmosphereGloveboxSchlenk technique; 2: With NaBEt3H in tetrahydrofuran T=25°C; 0.5 h; Inert atmosphereGloveboxSchlenk technique;
参考文献
Zhang, Lei; Peng, Dongjie; Leng, Xuebing; Huang, Zheng
Angewandte Chemie - International Edition, 2013 , vol. 52, # 13 p. 3676 - 3680
Angew. Chem., 2013 , vol. 52, # 13 p. 3676 - 3680,5
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; bis(1,1-diphenylphosphino)methane in dichloromethane T=20°C; 24 h;
参考文献
Yamamoto, Yasunori; Fujikawa, Rhyou; Umemoto, Tomokazu; Miyaura, Norio
Tetrahedron, 2004 , vol. 60, # 47 p. 10695 - 10700
反应条件
[(.eta.4-1,5-cyclooctadiene)Rh(.kappa.2-P,N-3-P(i)Pr2-2-NMe2-indenide)] in THF-d8 (tetrahydrofuran-d8) THF-d8, room temp., 2 molpercent of catalyst, 72 h; detected by NMR spectra;
参考文献
Organometallics, , vol. 25, # 25 p. 5965 - 5968
反应条件
n-butyllithium in tetrahydrofuran; hexane T=-78 - 20°C; 15 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 129, # 11 p. 3068 - 3069
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tripotassium phosphate monohydrate; P(t-Bu)2Me*HBF4 in water; tert-butyl alcohol T=60°C; Inert atmosphere;
参考文献
Joshi-Pangu, Amruta; Ma, Xinghua; Diane, Mohamed; Iqbal, Sidra; Kribs, Robert J.; Huang, Richard; Wang, Chao-Yuan; Biscoe, Mark R.
Journal of Organic Chemistry, 2012 , vol. 77, # 15 p. 6629 - 6633
反应条件
1: 3-phenylpropyl 2,4,6-triisopropylbenzoate With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in diethyl ether; hexane; cyclohexane T=-78°C; 1 h; Inert atmosphere; 2: 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in diethyl ether; hexane; cyclohexane T=-78 - 20°C; 2 h; Inert atmosphere;
参考文献
Roesner, Stefan; Brown, Christopher A.; Mohiti, Maziar; Pulis, Alexander P.; Rasappan, Ramesh; Blair, Daniel J.; Essafi, Stephanie; Leonori, Daniele; Aggarwal, Varinder K.
Chemical Communications, 2014 , vol. 50, # 31 p. 4053 - 4055
反应条件
1: N,N-diisopropyl-carbamic acid 3-phenyl-propyl ester With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in diethyl ether; hexane; cyclohexane T=-78°C; 5 h; Inert atmosphere; 2: 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in diethyl ether; hexane; cyclohexane T=-78°C; 12 h; Inert atmosphereReflux;
参考文献
Roesner, Stefan; Brown, Christopher A.; Mohiti, Maziar; Pulis, Alexander P.; Rasappan, Ramesh; Blair, Daniel J.; Essafi, Stephanie; Leonori, Daniele; Aggarwal, Varinder K.
Chemical Communications, 2014 , vol. 50, # 31 p. 4053 - 4055
