1,2-二甲基-3-碘苯合成路线 （共 16 条）
反应条件
1: With hydrogenchloride; sodium nitrite T=-15°C; 2: With potassium iodide Further stages.;
参考文献
Stewart, Scott G.; Spagnolo, Daniel; Polomska, Marta E.; Sin, Melvin; Karimi, Mahdad; Abraham, Lawrence J.
Bioorganic and Medicinal Chemistry Letters, 2007 , vol. 17, # 21 p. 5819 - 5824
反应条件
AgNO2; iodine in dichloromethane 72 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 30, # 29 p. 3769 - 3772
反应条件
boron trifluoride diethyl etherate in dichloromethane; acetonitrile T=-50°C; 2 h; Inert atmosphere; Overall yield = 85 percent;
参考文献
Chemistry - A European Journal, , vol. 18, # 39 p. 12232 - 12236
反应条件
1: Raney nickel / 150 °C / 73550.8 Torr / Hydrogenation 2: aqueous HCl / Diazotization.Behandlung der Diazoniumsalz-Loesung mit KI in der Waerme View Scheme
参考文献
Journal of Organic Chemistry, , vol. 6, p. 427,431
反应条件
1: 72 percent / cetyltrimethylammonium bromide, KMnO4 / H2O / 24 h / 50 - 60 °C 2: 88 percent / acetic anhydride / 1 h / Heating 3: Na-selectride / tetrahydrofuran / 4 h / 0 °C View Scheme
参考文献
Soucy, C.; Favreau, D.; Kayser, M. M.
Journal of Organic Chemistry, 1987 , vol. 52, # 1 p. 129 - 134
反应条件
1: With copper(l) iodide; 1,10-phenanthroline; potassium hydroxide in water; dimethyl sulfoxide T=20 - 100°C; Inert atmosphere; 2: With hydrogenchloride in water; dimethyl sulfoxide T=20°C; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 48, # 46 p. 8729 - 8732
反应条件
diethyl ether; sodium
参考文献
v. Auwers
Justus Liebigs Annalen der Chemie, 1919 , vol. 419, p. 111
参考文献
Klages; Liecke
Journal fuer Praktische Chemie (Leipzig), 1900 , vol. <2> 61, p. 322
反应条件
1: 72 percent / cetyltrimethylammonium bromide, KMnO4 / H2O / 24 h / 50 - 60 °C 2: 88 percent / acetic anhydride / 1 h / Heating View Scheme
参考文献
Soucy, C.; Favreau, D.; Kayser, M. M.
Journal of Organic Chemistry, 1987 , vol. 52, # 1 p. 129 - 134
反应条件
potassium permanganate; N-hexadecyl-N,N,N-trimethylammonium bromide in water T=50 - 60°C; 24 h;
参考文献
Soucy, C.; Favreau, D.; Kayser, M. M.
Journal of Organic Chemistry, 1987 , vol. 52, # 1 p. 129 - 134
