reduction in presence of triphenylphosphine under N2 atmosphere at room temperature, either in benzene or THF;; recrystn. from benzene, toluene or THF;;
in not given reaction of Ru(III)-acetylacetonate with five-fold excess of C5H5MgBr;; extraction with ether, multi-fold dissolution of the residue in ether or petroleum ether; after evapn. to dryness, the residue is sublimed and recrystd. from CCl4;;
参考文献
Journal of the American Chemical Society, , vol. 74, p. 6146 - 6147
in n-heptane react. of (Ru(aca)3) in heptane with CO and H2;; removal of the soln.; (Ru3(CO)12) remains in the autoclave; washing with heptane, sublimation at 90 ° and 10E-3 Torr;;
参考文献
Calderazzo, F.; L'Eplattenier, F.
Inorganic Chemistry, 1967 , vol. 6, p. 1220 - 1224
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Gmelin Handbook: Ru: SVol., 179, page 483 - 486
