(R)-(-)-2-戊醇合成路线 （共 42 条）
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst T=20 - 25°C; pH=7.4; 8 h; aq. phosphate bufferEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Agricultural and Food Chemistry, , vol. 58, # 10 p. 6328 - 6333
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst T=20 - 25°C; pH=7.4; 8 h; aq. phosphate bufferEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Agricultural and Food Chemistry, , vol. 58, # 10 p. 6328 - 6333
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst T=20 - 25°C; pH=7.4; 8 h; aq. phosphate bufferEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Agricultural and Food Chemistry, , vol. 58, # 10 p. 6328 - 6333
反应条件
Rhodococcus rhodochrous haloalkane dehalogenase T=21°C; pH=8.2; Tris sulfate bufferResolution of racemateEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 35 p. 6111 - 6115
反应条件
sec-alkylsulfatase Pisa1 T=30°C; pH=8.2; 24 h; aq. bufferEnzymatic reaction; optical yield given as percent ee;
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 9 p. 1737 - 1742
反应条件
1: triethylamine/sulphur trioxide complex; sodium hydride / paraffin oil 2: sec-alkylsulfatase Pisa1 / 24 h / 30 °C / pH 8.2 / aq. buffer; Enzymatic reaction View Scheme
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 9 p. 1737 - 1742
反应条件
Bradyrhizobium japonicum haloalkane dehalogenase in dimethyl sulfoxide T=37°C; pH=8.2; Tris bufferEnzymatic reaction; Kinetics;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 35 p. 6111 - 6115
反应条件
potassium hydroxide; hydrogen 2) MeOH, 1 atm., 3 d; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chemische Berichte, , vol. 119, # 6 p. 2013 - 2024
反应条件
T=135°C; unter Druck; (S)-2-fluoro-pentane;
参考文献
Journal of Research of the National Bureau of Standards (United States), vol. 31, p. 96
Chem.Abstr., , p. 5943
反应条件
NADP; tri-(hydroxymethyl)-methylamine; SADH from Thermoanaerobacter ethanolicus T=15°C; pH 8.9; temp.-dependent enantiospecificity; Rate constant;
参考文献
Pham, Van T.; Phillips, Robert S.; Ljungdahl, Lars G.
Journal of the American Chemical Society, 1989 , vol. 111, # 5 p. 1935 - 1936
