2,3-二氯六氟-2-丁烯合成路线 (共 73 条)
反应条件
hydrogen; copper on calcium fluoride T=250 - 450°C; 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 6 ;
反应条件
hydrogen; copper/nickel/chromium on calcium fluoride T=350 - 375°C; 0.00833333 - 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
hydrogen; palladium on calcium fluoride poisoned with lead acetate T=200 - 300°C; 0.000694444 - 0.00833333 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 8 ;
参考文献
Henne et al.
Journal of the American Chemical Society, 1947 , vol. 69, p. 1819
反应条件
potassium fluoride; 18-crown-6 ether in sulfolane T=190°C; 48 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chambers, Richard D.; Edwards, Andrew R.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 24 p. 3623 - 3627
反应条件
sodium hypochlorite in acetonitrile T=-10 - 10°C; 1 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Filyakova, T. I.; Matochkina, E. G.; Peschanskii, N. V.; Kodess, M. I.; Zapevalov, A. Ya.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 1.1 p. 20 - 28
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 1 p. 25 - 35
反应条件
sodium carbonate; Aliquatreg; 336 in water; toluene
T=35°C; 2 h;
参考文献
Mueller, Harald; Lerf, Anton; Fritz, Heinz P.
Liebigs Annalen der Chemie, 1991 , # 4 p. 395 - 396
反应条件
potassium fluoride; 18-crown-6 ether in sulfolane
T=190°C; 48 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chambers, Richard D.; Edwards, Andrew R.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 24 p. 3623 - 3627
反应条件
potassium carbonate in tetrahydrofuran
T=20°C; 24 h;
参考文献
BIOLIPOX AB
Patent: WO2007/51981 A1, 2007 ;
Location in patent: Page/Page column 54 ;
反应条件
hydrogen; copper on calcium fluoride
T=250 - 450°C; 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 6 ;