氯(二甲基硫化)金(I)合成路线 （共 39 条）
反应条件
aqua regia in methanol; water dissolving of Au in boiling aqua regia, redn. of vol. by boiling, addn. concd. HCl, redn. of volume; repeat this procedure; cooling to room tempp., addn. of CH3OH, dropwise addn. of SMe2 with min. light exposure withcontinous stirring; pptn., filtration, washing with methanol, diethyl ether and pentane, drying under vac.;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 24 p. 4601 - 4606
反应条件
in ethanol T=20°C; 2 h; Inert atmosphere;
参考文献
European Journal of Organic Chemistry, , # 31 p. 6218 - 6227
反应条件
in hydrogenchloride; dimethyl sulfoxide N2-atmosphere; refluxing Au (in concd. HCl/DMSO) for several h; in air; crystn. (freezer, overnight), filtration, extn. into MeOH, dissoln. in CH2Cl2, addn. of hexane, concn. (pptn.), collection (filtration), drying (vac.); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 551, # 1-2 p. 313 - 330
反应条件
in dichloromethane dropwise addn. of a soln. of trans-(PtCl2(SMe2)2) in CH2Cl2 to a stirred suspn. of 3 equiv of (AuCC-t-Bu) in CH2Cl2, removing of volatile compds. of the mixt. (reduced pressure, after 3 h); drying (vac.);
参考文献
Organometallics, , vol. 8, p. 2055 - 2061
反应条件
hydrogenchloride in hydrogenchloride 90°C; 2 h;; cooled; washed with pentane/EtOH; dried on filter paper; elem. anal.;;
参考文献
Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), , vol. 41, # 3 p. 498 - 506,391 - 397
反应条件
in neat (no solvent) dissolvung of Au powder in conc. HCl-DMSO mixt.;
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 34, # 5 p. 360 - 366
反应条件
methyllithium in diethyl ether addn. of 3,3-dimethylbut-1-yne in (C2H5)2O to CH3Li in dry (C2H5)2O under N2 (0°C), warming (room temp.), addn. to a suspn. of AuCl(SMe2) in (C2H5)2O (-78°C), warming (room temp.), stirring (1 h), addn. of a satd. NH4Cl-soln. (0°C); sepn. of the organic layer;
参考文献
Manojlovic-Muir, Ljubica; Henderson, Allan N.; Treunicht, Ilse; Puddephatt, Richard J.
Organometallics, 1989 , vol. 8, p. 2055 - 2061
反应条件
sulfuric acid in sulfuric acid; water byproducts: HCN, K2SO4; conc. H2SO4 was added in excess to intermediate complex; elem. anal.;
参考文献
Akhtar; Isab; Hassan
Journal of Thermal Analysis and Calorimetry, 2000 , vol. 61, # 1 p. 119 - 125
反应条件
in dichloromethane byproducts: S(CH3)2; stirring at room temp. for 0.5 h; removing of solvent and SMe2 in vac., dissolving in CH2Cl2, chromy. on silica gel and evapn.; elem. anal.;
参考文献
Jia, Guochen; Puddephatt, Richard J.; Vittal, Jagadese J.
Journal of Organometallic Chemistry, 1993 , vol. 449, # 1-2 p. 211 - 217
反应条件
in acetone addn. of soln. of dppe (1 equiv.) in acetone to suspn. of (AuCl(SMe)2) (2 equiv.) in acetone; stirring for 2 h; pptn., filtration, washing with acetone, diethyl ether and pentane, drying under vac.;
参考文献
Brandys, Marie-Claude; Jennings, Michael C.; Puddephatt, Richard J.
Journal of the Chemical Society, Dalton Transactions, 2000 , # 24 p. 4601 - 4606
