3-三甲基甲硅烷基丙炔醛合成路线 （共 23 条）
参考文献
Chauvin, Remi
Tetrahedron Letters, 1995 , vol. 36, # 3 p. 401 - 404
反应条件
manganese(IV) oxide; silica gel T=25°C; 70 h;
参考文献
Mareev, Alexander V.; Medvedeva, Alevtina S.; Khatashkeev, Alexander V.; Afonin, Andrey V.
Mendeleev Communications, 2005 , # 6 p. 263 - 265
反应条件
hydrogenchloride; n-butyllithium in diethyl ether; hexane; N,N-dimethyl-formamide
参考文献
Institute of Medicinal Molecular Design, Inc.
Patent: EP1145718 A1, 2001 ;
反应条件
diisobutylaluminium hydride in dichloromethane T=-78°C; 0.25 h;
参考文献
Yamada, Hiroko; Kushibe, Kayo; Okujima, Tetsuo; Uno, Hidemitsu; Ono, Noboru
Chemical Communications, 2006 , # 4 p. 383 - 385
反应条件
1: 73.66 g / aq. HCl / tetrahydrofuran; hexane / 1 h / 20 °C 2: PCC / CH2Cl2 / 2 h / 0 - 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 10, # 20 p. 5087 - 5110
反应条件
1: 65 percent / BuLi / tetrahydrofuran / 2 h / -78 to 0 deg C 2: 79 percent / PCC / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Synthesis, , # 11 p. 979 - 982
反应条件
manganese(IV) oxide; n-butyllithium; citric acid 1.) THF; 2.) MeOH; 3.) CH2Cl2; Yield given. Multistep reaction;
参考文献
Tetrahedron Letters, , vol. 38, # 47 p. 8193 - 8196
反应条件
(i) nBuLi, (ii) /BRN= 906769/; Multistep reaction;
参考文献
Synthesis, , p. 307 - 309
反应条件
1: 81 percent / p-toluenesulfonic acid / benzene / Heating 2: 1.) BuLi / 1.) THF, -65 deg C, 30 min; 2.) THF, overnight, -65 deg C to 25 deg C 3: 63 percent / H2SO4 / acetone; H2O / 5 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 39, # 19 p. 3073 - 3082
反应条件
1: 94 percent / ethanol / 3.5 h / Heating 2: NaBH3CN, conc HCl / dimethylformamide; tetrahydrothiophene 1,1-dioxide; pentane / 78 h / 40 - 60 °C / pH 1-2 View Scheme
参考文献
Danheiser, Rick L.; Carini, David J.
Journal of Organic Chemistry, 1980 , vol. 45, # 19 p. 3925 - 3927
