1,1,2,2-四叔丁基乙烯合成路线 （共 14 条）
反应条件
lithium aluminium tetrahydride; titanium(III) chloride in tetrahydrofuran
T=75°C; 6 h; Irradiation;
参考文献
Boehrer, Gerald; Knorr, Rudolf; Boehrer, Petra; Schubert, Bernhard
Liebigs Annales, 1997 , # 1 p. 193 - 202
反应条件
1: (i) Et2O, (ii) /BRN= 473192/
2: aq. NaOH / dioxane
View Scheme
参考文献
Bartlett,P.D.; Tidwell,T.T.
Journal of the American Chemical Society, 1968 , vol. 90, p. 4421 - 4428
反应条件
1: (i) Et2O, (ii) /BRN= 473192/
2: aq. NaOH / dioxane
View Scheme
参考文献
Bartlett,P.D.; Tidwell,T.T.
Journal of the American Chemical Society, 1968 , vol. 90, p. 4421 - 4428
反应条件
sodium hydroxide in 1,4-dioxane
参考文献
Bartlett,P.D.; Tidwell,T.T.
Journal of the American Chemical Society, 1968 , vol. 90, p. 4421 - 4428
反应条件
1: methyl-isopropyl ketone With titanium tetrachloride; lithium in THF-d8 (tetrahydrofuran-d8)
T=20°C; McMurry reaction; 24 h;
2: pivalaldehyde in THF-d8 (tetrahydrofuran-d8)
Further stages.;
参考文献
Villiers, Claude; Ephritikhine, Michel
Chemistry - A European Journal, 2001 , vol. 7, # 14 p. 3043 - 3051
反应条件
1: 63 percent / Na / diethyl ether / 1.) reflux, 0.5 h, 2.) r.t., overnight
2: 45 percent / diethyl ether; pentane
3: 81 percent / 96 h / 120 °C
4: 60 percent / Ac2O / 3.5 h / 90 °C
View Scheme
参考文献
Boehrer, Gerald; Knorr, Rudolf; Boehrer, Petra; Schubert, Bernhard
Liebigs Annales, 1997 , # 1 p. 193 - 202
参考文献
Krebs, Adolf; Born, Wolfgang; Kaletta, Bernd; Nickel, Wolf-Ulrich; Rueger, Wolfgang
Tetrahedron Letters, 1983 , vol. 24, # 44 p. 4821 - 4824
反应条件
1: 43 percent / diethyl ether / 1 h / -50 °C
2: 45 percent / diethyl ether; pentane
3: 81 percent / 96 h / 120 °C
4: 60 percent / Ac2O / 3.5 h / 90 °C
View Scheme
参考文献
Boehrer, Gerald; Knorr, Rudolf; Boehrer, Petra; Schubert, Bernhard
Liebigs Annales, 1997 , # 1 p. 193 - 202
反应条件
lithium aluminium tetrahydride; titanium(III) chloride
T=80°C; 96 h;
参考文献
Boehrer, Gerald; Knorr, Rudolf; Boehrer, Petra; Schubert, Bernhard
Liebigs Annales, 1997 , # 1 p. 193 - 202
反应条件
1: 45 percent / diethyl ether; pentane
2: 81 percent / 96 h / 120 °C
3: 60 percent / Ac2O / 3.5 h / 90 °C
View Scheme
参考文献
Boehrer, Gerald; Knorr, Rudolf; Boehrer, Petra; Schubert, Bernhard
Liebigs Annales, 1997 , # 1 p. 193 - 202
