1: phenyl-magnesium chloride With CuCN*2LiCl in tetrahydrofuran T=-20°C; 2: (2,2-diphenylvinyl)trifluoromethnesulfonate With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C;

1,1'-bis-(diphenylphosphino)ferrocene; 2-phenyl-1,2,4-triazol-3-ylidene borane; palladium diacetate in tetrahydrofuran Reflux;

1: p-methoxy-phenylmagnesium chloride With CuCN*2LiCl in tetrahydrofuran T=-20°C; 2: (2,2-diphenylvinyl)trifluoromethnesulfonate With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C;

palladium diacetate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in water; toluene T=80°C; Suzuki-Miyaura coupling; 24 h; Inert atmosphere;