(±)-4-氯苯乙烯环氧化物合成路线 （共 77 条）
反应条件
1,1,1-trifluoropropanone; dihydrogen peroxide
参考文献
Capriati, Vito; Florio, Saverio; Luisi, Renzo; Salomone, Antonio
Organic Letters, 2002 , vol. 4, # 14 p. 2445 - 2448
反应条件
iodosylbenzene; 5,5'-dinitro-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate) in acetonitrile T=25°C;
参考文献
Collman, James P.; Kodadek, Thomas; Brauman, John I.
Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2588 - 2594
反应条件
1: trimethyl-sulfonium iodide With sodium hydroxide in water Corey-Chaykovsky reaction; 0.166667 h; 2: 4-chlorobenzaldehyde With 1,3-bis(3,5-bis(trifluoromethyl)phenyl)urea in dichloromethane; water T=20°C; 15 h; Inert atmosphere;
参考文献
Kavanagh, Sarah A.; Piccinini, Alessandro; Fleming, Eimear M.; Connon, Stephen J.
Organic and Biomolecular Chemistry, 2008 , vol. 6, # 8 p. 1339 - 1343
反应条件
oxygen; isobutyraldehyde in 1,2-dichloro-ethane T=40°C; 6 h;
参考文献
Sawaki, Yasuhiko; Ogata, Yoshiro
Journal of Organic Chemistry, 1984 , vol. 49, # 18 p. 3344 - 3349
反应条件
1: With tetramethylene sulfide; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine in dichloromethane T=20°C; 0.416667 h; Inert atmosphere; 2: With 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-25,45-catenodi(phosphazene) in tetrahydrofuran; dichloromethane T=20°C; Inert atmosphere;
参考文献
Piccinini, Alessandro; Kavanagh, Sarah A.; Connon, Paul B.; Connon, Stephen J.
Organic Letters, 2010 , vol. 12, # 3 p. 608 - 611
反应条件
phthalocyanine blue; tetrabutylammonium hydrogen monopersulfate in water T=70°C; 0.25 h; chemoselective reaction;
参考文献
Rezaeifard, Abdolreza; Jafarpour, Maasoumeh; Naeimi, Atena; Mohammadi, Khosro
Journal of Molecular Catalysis A: Chemical, 2012 , vol. 357, p. 141 - 147
反应条件
caesium carbonate in tetrahydrofuran T=80°C; 12 h;
参考文献
Forbes, David C.; Bettigeri, Sampada V.; Patrawala, Samit A.; Pischek, Susanna C.; Standen, Michael C.
Tetrahedron, 2009 , vol. 65, # 1 p. 70 - 76
参考文献
Zeneca Limited
Patent: US5703246 A1, 1997 ;
反应条件
methyllithium in tetrahydrofuran; diethyl ether T=0 - 20°C; 1.5 h;
参考文献
Concellon, Jose M; Cuervo, Humildad; Fernandez-Fano, Ramon
Tetrahedron, 2001 , vol. 57, # 43 p. 8983 - 8987
反应条件
tetramethylene sulfide; diethylzinc in 1,2-dichloro-ethane 48 h; Ambient temperature;
参考文献
Aggarwal, Varinder K.; Ali, Amjad; Coogan, Michael P.
Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8628 - 8629
