2-甲基-1,3,6-三氧杂环辛烷合成路线 (共 6 条)
反应条件
sulfuric acid in various solvent(s) T=250°C; Further byproducts given;
参考文献
Trofimov, B. A.; Lavrov, V. I.; Parshina, L. N.; Stankevich, V. K.
J. Appl. Chem. USSR (Engl. Transl.), 1980 , vol. 53, # 4 p. 883 - 888,693 - 698
反应条件
methanol; boron trifluoride; mercury(II) oxide
参考文献
Nieuwland; Vogt; Foohey
Journal of the American Chemical Society, 1930 , vol. 52, p. 1022
反应条件
Amberlite IR-120 sulphonic acid resin in dichloromethane; Petroleum ether Heating;
参考文献
Gold, Victor,; Sghibartz, Cristian M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 2 p. 453 - 458
反应条件
Dowex 50X8 (H+ form) in toluene 5 h; Heating;
参考文献
Smirnov, I. P.; Tsilevich, T. L.; Kochetkova, S. V.; Gottikh, B. P.; Shchaveleva, I. L.; Florent'ev, V. L.
Russian Journal of Bioorganic Chemistry, 1995 , vol. 21, # 10 p. 684 - 688
Bioorganicheskaya Khimiya, 1995 , vol. 21, # 10 p. 790 - 794
反应条件
unter vermindertem Druck;
参考文献
Hurd; Botteron
Journal of the American Chemical Society, 1946 , vol. 68, p. 1201
反应条件
water; hydrogenchloride in 1,4-dioxane Ambient temperatureeffect of alkali and alkaline earth metal chlorides and concentrations of HCl; Rate constant;
参考文献
Baker, David S.; Gold, Victor; Sghibartz, Cristian M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 1121 - 1128