2,2-二甲基-2,3-二氢-1H-2-硅杂茚合成路线 （共 6 条）
反应条件
1.1: magnesium / tetrahydrofuran / |Inert atmosphere 1.2: 24 h / 25 °C / |Inert atmosphere 2.1: [RhCl(η2:η2-cycloocta-1,5-diene)]2; 1,3-bis-(diphenylphosphino)propane / 1,4-dioxane / 24 h / 25 - 180 °C View Scheme
参考文献
Kuninobu, Yoichiro; Nakahara, Takahiro; Takeshima, Hirotaka; Takai, Kazuhiko
Organic Letters, 2013 , vol. 15, # 2 p. 426 - 428
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; magnesium in tetrahydrofuran 1.) r.t., overnight, 2.) reflux, 3 h;
参考文献
Shimizu, Nobujiro; Osajima, Erika; Tsuno, Yuho
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 4 p. 1145 - 1152
反应条件
magnesium in tetrahydrofuran 8 h; Heating;
参考文献
Traven', V. F.; Eismont, M. Yu.; Redchenko, V. V.; Stepanov, B. I.
J. Gen. Chem. USSR (Engl. Transl.), 1980 , vol. 50, # 9 p. 2007 - 2016,1621 - 1628
反应条件
n-butyllithium; potassium tert-butylate 1.) hexane, reflux, 1 h, 2.) pentane; Yield given. Multistep reaction;
参考文献
Bates, Robert B.; Ogle, Craig A.
Journal of Organic Chemistry, 1982 , vol. 47, # 20 p. 3949 - 3952
参考文献
Rizvi,S.Q.A. et al.
Journal of Organometallic Chemistry, 1973 , vol. 63, p. 67 - 77
参考文献
Nametkin,N.S. et al.
Doklady Chemistry, 1964 , vol. 154, p. 64 - 67
Doklady Akademii Nauk SSSR, 1964 , vol. 154, p. 383 - 386
