(三-2-丙烯-1-基硅烷基)-苯合成路线 （共 61 条）
反应条件
1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water T=20°C; 1 h; 2: 2-Chloro-1-trifluoromethylbenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water T=80°C; 3 h;
参考文献
Sahoo, Akhila K.; Nakao, Yoshiaki; Hiyama, Tamejiro
Chemistry Letters, 2004 , vol. 33, # 5 p. 632 - 633
反应条件
1.1: TBAF*3H2O / dimethylsulfoxide; H2O / 1 h / 20 °C 1.2: 98 percent / PCy3 / PdCl2 / dimethylsulfoxide; H2O / 12 h / 80 °C 2.1: TBAF*3H2O / tetrahydrofuran; H2O / 1 h / 20 °C 2.2: 87 percent / 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl / [(η3-C3H5)PdCl]2 / dimethylsulfoxide; H2O / 8 h / 80 °C View Scheme
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water T=20°C; 1 h; 2: 3-chloro-4-methoxynitrobenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water T=80°C; 3 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water T=20°C; 1 h; 2: 4-methyl-chlorobenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water T=80°C; 14 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in water; dimethyl sulfoxide T=20°C; 1 h; 2: para-bromotoluene With tri-cyclo-hexyl-phosphine; palladium dichloride in water; dimethyl sulfoxide T=80°C; 3 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
tetrabutyl ammonium fluoride; palladium dichloride; tri-cyclo-hexyl-phosphine in water; dimethyl sulfoxide
T=80°C; 2 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
tetrabutyl ammonium fluoride; palladium dichloride; tri-cyclo-hexyl-phosphine in water; dimethyl sulfoxide
T=80°C; 2 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: 1-chloro-3,4-methylenedioxybenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 14 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in water; dimethyl sulfoxide
T=20°C; 1 h;
2: 1-bromo-4-(1,1-dimethylethyl)benzene With tri-cyclo-hexyl-phosphine; palladium dichloride in water; dimethyl sulfoxide
T=80°C; 4 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: PTAS With tetrabutyl ammonium fluoride in water; dimethyl sulfoxide
T=20°C; 1 h;
2: 3-(bromo)-quinoline With tri-cyclo-hexyl-phosphine; palladium dichloride in water; dimethyl sulfoxide
T=80°C; 2 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
