1,1'-(2,2-二溴-1,1-乙烯二基)二苯合成路线 (共 52 条)
反应条件
Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=130°C; 12 h;
参考文献
Shimizu, Masaki; Nagao, Ikuhiro; Kiyomoto, Shin-Ichi; Hiyama, Tamejiro
Australian Journal of Chemistry, 2012 , vol. 65, # 9 p. 1277 - 1284,8
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Shimizu, Masaki; Nagao, Ikuhiro; Kiyomoto, Shin-Ichi; Hiyama, Tamejiro
Australian Journal of Chemistry, 2012 , vol. 65, # 9 p. 1277 - 1284
反应条件
1: tetrakis(triphenylphosphine) palladium(0); copper(l) iodide; diisopropylamine / 75 °C 2: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 °C 3: [Ru(HB(pz)3)(PPh3)(MeCN)2]PF6 / dichloromethane / 80 °C View Scheme
参考文献
Barnes, Jonathan C.; Juricek, Michal; Strutt, Nathan L.; Frasconi, Marco; Sampath, Srinivasan; Giesener, Marc A.; McGrier, Psaras L.; Bruns, Carson J.; Stern, Charlotte L.; Sarjeant, Amy A.; Stoddart, J. Fraser
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 183 - 192
反应条件
1: 2.) hydrogen peroxide / 1.) THF, reflux, 3 h 2: 80 percent / bromine / acetic acid / 1 h / Ambient temperature 3: lithium diphenylphosphide / tetrahydrofuran / 1 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 8 p. 1689 - 1695
反应条件
NiBr2(PPh3)2; tetraethylammonium iodide; zinc in tetrahydrofuran Ambient temperature;
参考文献
Chemistry Letters, , p. 2005 - 2006
反应条件
NiBr2(PPh3)2; zinc in tetrahydrofuran T=50°C;
参考文献
Chemistry Letters, , p. 2005 - 2006
反应条件
NiBr2(PPh3)2; tetraethylammonium iodide; zinc in tetrahydrofuran Ambient temperature;
参考文献
Chemistry Letters, , p. 2005 - 2006
反应条件
NiBr2(PPh3)2; zinc in tetrahydrofuran T=50°C;
参考文献
Chemistry Letters, , p. 2005 - 2006
反应条件
lithium in tetrahydrofuran; diethyl ether; pentane T=-110 - -80°C; 3 h; Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 566, # 1-2 p. 143 - 149
反应条件
NiBr2(PPh3)2; tetraethylammonium iodide; zinc in tetrahydrofuran Ambient temperature;
参考文献
Chemistry Letters, , p. 2005 - 2006
反应条件
NiBr2(PPh3)2; zinc in tetrahydrofuran T=50°C;
参考文献
Chemistry Letters, , p. 2005 - 2006