(E)-1-(4-甲氧基苯基)-4,4-二甲基戊-1-烯-3-酮合成路线 （共 4 条）
反应条件
sodium hydroxide; ethanol
参考文献
Seguin,J.-P. et al.
Bulletin de la Societe Chimique de France, 1974 , p. 167 - 172
反应条件
4-tolylthallium(III) bis(trifluoroacetate); titanium tetrachloride 1.) benzene, RT, 30 min, 2.) THF, -78 deg C, 1.5 h, RT, 1 h; Yield given. Multistep reaction;
参考文献
Moriarty, Robert M.; Penmasta, Raju; Prakash, Indra; Awasthi, Alok K.
Journal of Organic Chemistry, 1988 , vol. 53, # 5 p. 1022 - 1025
反应条件
1: 70 percent / urea hydrogen peroxide, DBU, immobilised poly-L-leucine / tetrahydrofuran / 28 h 2: 84 percent / MCPBA, KF / CH2Cl2 / 24 h 3: 90 percent / toluene / 17 h / Heating 4: 94 percent / xylene / 216 h / Heating 5: K2CO3 / ethyl acetate 6: pyridine, DMAP View Scheme
参考文献
Adger, Brian M.; Barkley, James V.; Bergeron, Sophie; Cappi, Michael W.; Flowerdew, Benjamin E.; Jackson, Mark P.; McCague, Ray; Nugent, Thomas C.; Roberts, Stanley M.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 23 p. 3501 - 3507
反应条件
1: 70 percent / urea hydrogen peroxide, DBU, immobilised poly-L-leucine / tetrahydrofuran / 28 h
2: 84 percent / MCPBA, KF / CH2Cl2 / 24 h
3: 90 percent / toluene / 17 h / Heating
4: 94 percent / xylene / 216 h / Heating
5: K2CO3 / ethyl acetate
View Scheme
参考文献
Adger, Brian M.; Barkley, James V.; Bergeron, Sophie; Cappi, Michael W.; Flowerdew, Benjamin E.; Jackson, Mark P.; McCague, Ray; Nugent, Thomas C.; Roberts, Stanley M.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 23 p. 3501 - 3507
