1,2-二(2-噻吩基)乙炔合成路线 （共 26 条）
反应条件
sodium hydroxide; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); BnEt3(+)* Cl(-) in water; benzene
T=40°C; 40 h;
参考文献
Rossi, Renzo; Carpita, Adriano; Lezzi, Alessandro
Tetrahedron, 1984 , vol. 40, # 14 p. 2773 - 2780
反应条件
bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide
T=110°C; 3 h;
参考文献
Park, Kyungho; Bae, Goun; Moon, Jeongju; Choe, Jaehoon; Song, Kwang Ho; Lee, Sunwoo
Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6244 - 6251
反应条件
triethylamine; copper(l) iodide in N,N-dimethyl-formamide
T=60°C; 12 h;
参考文献
Pal, Manojit; Kundu, Nitya G.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 5 p. 449 - 451
反应条件
1: 1,2-bis(methylthio)acetylene With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether in tetrahydrofuran
0.166667 h; Inert atmosphere;
2: (2-thienyl)ZnI*LiCl in tetrahydrofuran
T=50°C; 20 h; Inert atmosphere;
参考文献
Melzig, Laurin; Metzger, Albrecht; Knochel, Paul
Chemistry - A European Journal, 2011 , vol. 17, # 10 p. 2948 - 2956
反应条件
sodium hydroxide; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); phenylmethyltriethylammonium bromide in benzene
34 h; Heating;
参考文献
Ng, Siu-Choon; Ong, Teng-Teng; Chan, Hardy S. O.
Journal of Materials Chemistry, 1998 , vol. 8, # 12 p. 2663 - 2669
反应条件
tris[N-(tert-butyl)(3,5-dimethylphenyl)amido]molybdenum(VI) propylidyne; tris(2-hydroxy-5-nitro-benzyl)amine in tetrachloromethane
T=40°C; 4 h; Inert atmosphere;
参考文献
Jyothish, Kuthanapillil; Zhang, Wei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 15 p. 3435 - 3438
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-60 - 0°C; 0.5 h; Yield given;
参考文献
Mouries, Virginie; Waschbuesch, Rachel; Carran, John; Savignac, Philippe
Synthesis, 1998 , # 3 p. 271 - 274
反应条件
pyridine; Cu2Cl2; oxygen
Glaser homocoupling;
参考文献
Rodriguez, J. Gonzalo; Lafuente, Antonio; Rubio, Laura
Tetrahedron Letters, 2004 , vol. 45, # 29 p. 5685 - 5688
反应条件
potassium hydroxide in methanol; acetonitrile
T=50°C;
参考文献
D'Auria
Synthetic Communications, 1992 , vol. 22, # 16 p. 2393 - 2399
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine
T=20°C; Sonogashira Cross-Coupling; 4 h; Inert atmosphere;
参考文献
Yu, Yue; Huang, Liangbin; Wu, Wanqing; Jiang, Huanfeng
Organic Letters, 2014 , vol. 16, # 8 p. 2146 - 2149
