戊烷-1,5-二(溴化镁)合成路线 （共 50 条）
反应条件
ethylene dibromide in diethyl ether T=19.4 - 30°C; Grignard Reaction; Heating / refluxIndustry scale; Product distribution / selectivity;
参考文献
WO2009/61581 A1, ;
Page/Page column 9-11 ;
反应条件
magnesium in tetrahydrofuran T=0°C;
参考文献
Tetrahedron, , vol. 43, # 4 p. 663 - 668
反应条件
in tetrahydrofuran 1 h;
参考文献
Canonne, P.; Boulanger, R.; Chantegrel, B.
Tetrahedron, 1987 , vol. 43, # 4 p. 663 - 668
参考文献
Nenitzescu; Necsoiu
Journal of the American Chemical Society, 1950 , vol. 72, p. 3483
参考文献
Grignard; Vignon
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1907 , vol. 144, p. 1359
反应条件
diethyl ether T=-15 - -10°C; zuletzt bei Siedetemperatur;
参考文献
Brown; Jones
Journal of the Chemical Society, 1946 , p. 781
反应条件
in diethyl ether T=20 - 35°C; Industry scale;
参考文献
DOW CORNING CORPORATION
Patent: WO2009/61581 A1, 2009 ;
Location in patent: Page/Page column 9-10 ;
反应条件
1: diethyl ether 2: diethyl ether View Scheme
参考文献
West
Journal of the American Chemical Society, 1954 , vol. 76, p. 6015
参考文献
Barton,T.J.; Revis,A.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3802
反应条件
in tetrahydrofuran Ambient temperature; Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 22, # 50 p. 4995 - 4998
