反式-2-苯基-1-环已醇合成路线 （共 72 条）
反应条件
titanium(III) tetrahydroborate in dichloromethane T=-20°C; 0.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 34, # 1 p. 171 - 174
反应条件
2,6-di-tert-butyl-4-methyl-phenol; diisobutylaluminium hydride in toluene ΔH(excit.), ΔS(excit.); influence of reaction temperature and time on the diastereoselectivity of the reduction; Thermodynamic dataProduct distribution;
参考文献
Journal of the Chemical Society. Perkin Transactions 2, , # 3 p. 593 - 595
反应条件
copper(l) chloride in tetrahydrofuran T=0°C; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 134, # 38 p. 15992 - 15999
反应条件
lithium aluminium tetrahydride in diethyl ether 6 h; Heating; Yield given;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 324, # 5 p. 725 - 734
反应条件
1.1: ZnBr2 / tetrahydrofuran / 0.67 h / 0 °C 1.2: CuCN*2LiCl / tetrahydrofuran / 0.58 h / -10 - 0 °C 1.3: 90 percent / tetrahydrofuran / 3 h / -78 - -50 °C 2.1: 25 mg / LiAlH4 / tetrahydrofuran / 7 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 53, # 39 p. 13427 - 13448
反应条件
lithium borohydride; borane-THF in tetrahydrofuran Ambient temperatureselective LiBH4*BH3 reduction of epoxides; cis-trans ratio; retention of configuration; Product distribution;
参考文献
Lynch; Choi; Churchill; Volante; Reamer; Ball
Journal of Organic Chemistry, 1997 , vol. 62, # 26 p. 9223 - 9228
反应条件
1: 68 percent / diethyl ether; benzene / 8 h / Heating 2: LiAlH4 / diethyl ether / 6 h / Heating View Scheme
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 324, # 5 p. 725 - 734
反应条件
1: thiolacetic acid potassium salt / N,N-dimethyl-formamide 2: borane-THF / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 68, # 22 p. 4320 - 4327
反应条件
1: pyridine / 0 °C 2: thiolacetic acid potassium salt / N,N-dimethyl-formamide 3: borane-THF / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 68, # 22 p. 4320 - 4327
反应条件
1: bis(cyclopentadienyl)dimethyltitanium / tetrahydrofuran / 16 h / Inert atmosphere; Reflux 2: water; potassium carbonate / tetrahydrofuran; acetone / 16 h / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 35 p. 8891 - 8894
