1-乙基-2,3,4,5,6-五氟苯合成路线 (共 7 条)
反应条件
hydrogen; dicobalt octacarbonyl 1.) benzene, room temperature, 80 atm, 2.) 90 deg C, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Ojima; Okabe; Kato; Kwon; Horvath
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 150 - 157
反应条件
hydrogen; dodecacarbonyltetrarhodium(0); dicobalt octacarbonyl in 1,4-dioxane 1.) 1100 psi of CO; 700 psi of H2; 60 deg C, 6 h; 2.) 125 deg C, 5 h; Yield given. Yields of byproduct given;
参考文献
Ojima; Okabe; Kato; Kwon; Horvath
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 150 - 157
反应条件
T=-40°C; 0.333333 h; Inert atmosphere;
参考文献
Bilir, Vural; Frohn, Hermann-Josef
Acta Chimica Slovenica, 2013 , vol. 60, # 3 p. 505 - 512
反应条件
tri-ruthenium(0)dodecacarbonyl T=70°C; 18 h; Yields of byproduct given;
参考文献
Ojima, Iwao; Fuchikami, Takamasa; Yatabe, Momoko
Journal of Organometallic Chemistry, 1984 , vol. 260, # 3 p. 335 - 346
反应条件
in tetrahydrofuran T=60°C; 48 h; Inert atmosphere;
参考文献
Sun, Yunqiang; Sun, Hongjian; Jia, Jiong; Du, Aiqin; Li, Xiaoyan
Organometallics, 2014 , vol. 33, # 4 p. 1079 - 1081
反应条件
(i) Li, (ii) /BRN= 1683438/; Multistep reaction;
参考文献
Budnik,A.G. et al.
Zhurnal Organicheskoi Khimii, 1974 , vol. 10, # 2 p. 344 - 350,343 - 348
反应条件
Rh(acac)(Ph2PCC-t-Bu)2 in benzene-d6 18 h; Product distribution; Further Variations:Catalysts;
参考文献
Vogels, Christopher M.; Decken, Andreas; Westcott, Stephen A.
Canadian Journal of Chemistry, 2006 , vol. 84, # 2 p. 146 - 153