三甲基-(3-三甲基硅烷基丁-1,3-二烯-2-基)硅烷合成路线 （共 12 条）
反应条件
1: benzoyl chloride With aluminium trichloride in dichloromethane T=0°C; 2: 2,3-bis(trimethylsilyl)-buta-1,3-diene in dichloromethane T=0°C; Further stages.;
参考文献
Babudri, Francesco; Cicco, Stefania R.; Farinola, Gianluca M.; Lopez, Linda C.; Naso, Francesco; Pinto, Vita
Chemical Communications, 2007 , # 36 p. 3756 - 3758
反应条件
1: benzoyl chloride With aluminium trichloride in dichloromethane T=0°C; 2: 2,3-bis(trimethylsilyl)-buta-1,3-diene in dichloromethane T=0°C; Further stages.;
参考文献
Babudri, Francesco; Cicco, Stefania R.; Farinola, Gianluca M.; Lopez, Linda C.; Naso, Francesco; Pinto, Vita
Chemical Communications, 2007 , # 36 p. 3756 - 3758
反应条件
1: benzoyl chloride With aluminium trichloride in dichloromethane T=0°C; 18 h; 2: 2,3-bis(trimethylsilyl)-buta-1,3-diene in dichloromethane T=0°C; Further stages. Title compound not separated from byproducts.;
参考文献
Babudri, Francesco; Cicco, Stefania R.; Farinola, Gianluca M.; Lopez, Linda C.; Naso, Francesco; Pinto, Vita
Chemical Communications, 2007 , # 36 p. 3756 - 3758
反应条件
1: 1-bromo-1-trimethylsilylethene
2: 6-iodohexene With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
反应条件
1: 1-bromo-1-trimethylsilylethene
2: dodecyl bromide With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
反应条件
(i) Mg, THF, (ii) (hydrolysis), aq. HCl; Multistep reaction;
参考文献
Bock,H.; Seidl,H.
Journal of the American Chemical Society, 1968 , vol. 90, p. 5694 - 5700
反应条件
methyllithium
THF + ether, -78 deg C; Yield given. Multistep reaction;
参考文献
Reich, Hans J.; Yelm, Kenneth E.; Reich, Ieva L.
Journal of Organic Chemistry, 1984 , vol. 49, # 18 p. 3438 - 3440
反应条件
1: 1.) bromine; 2.) diethylamine / 1.) -78 deg C
2: Mg / tetrahydrofuran / Heating
View Scheme
参考文献
Ding, Yi-Xiang; Weber, William P.
Journal of Organometallic Chemistry, 1988 , vol. 341, p. 267 - 272
反应条件
1: CrO3 / H2SO4
2: methanol
3: BuLi, tetramethylwenediamine / from -78 deg C to RT.
View Scheme
参考文献
Garratt, Peter J.; Tsotinis, Andrew
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2761 - 2762
反应条件
1: methanol
2: BuLi, tetramethylwenediamine / from -78 deg C to RT.
View Scheme
参考文献
Garratt, Peter J.; Tsotinis, Andrew
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2761 - 2762
