7-甲基-3,4-二氢-2H-1-萘酮合成路线 （共 41 条）
反应条件
1: Zn-Hg, aq. HCl 2: AlCl3 3: sulfur View Scheme
参考文献
Coombs,M.M.; Jaitly,S.B.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 230 - 234
反应条件
1: BF3*Et2O / 1.) 60 deg C, 2 h; 2.) 100 deg C, 2 h 2: POCl3 / pyridine / 2 h / Heating 3: 67 percent / S, 10percent Pd-C / various solvent(s) / 2 h / Heating 4: 67 percent / Br2 / CCl4 / 3 h / 60 °C / Irradiation 5: 1.25 h / 60 °C 6: 2N HCl / 0.08 h View Scheme
参考文献
Jouanno, Chantal; Floc'h, Yves Le; Gree, Rene
Bulletin des Societes Chimiques Belges, 1995 , vol. 104, # 1 p. 49 - 54
参考文献
Baker; Hopkins
Journal of medicinal chemistry, 1970 , vol. 13, # 1 p. 87 - 89
反应条件
1: xylene; NaNH2 / anschliessendes Erwaermen mit Phenaethylbromid und wenig Phenaethyljodid
2: LiAlH4; diethyl ether
3: H2SO4
4: palladium/charcoal / 320 °C
View Scheme
参考文献
Buchta; Guellich
Chemische Berichte, 1959 , vol. 92, p. 916,918
反应条件
hydrogenchloride; Zn–Hg amalgam in water; toluene
20 h; Heating;
参考文献
Collins, Michael J.; Gready, Jill E.; Sternhell, Sever; Tansey, Charles W.
Australian Journal of Chemistry, 1990 , vol. 43, p. 1547 - 1557
反应条件
ethanol; aluminium amalgam; benzene
Erhitzen des Reaktionsprodukts in Eisessig;
参考文献
Sen Gupta,S.C. et al.
Journal of the Indian Chemical Society, 1960 , vol. 37, # 10 p. 597 - 602
反应条件
Kochen des Reaktionsprodukts mit Essigsaeure;
参考文献
Newman
Journal of the American Chemical Society, 1940 , vol. 62, p. 1683,1686
反应条件
1: amalgamated aluminium; ethanol; benzene / Erhitzen des Reaktionsprodukts in Eisessig
2: xylene
3: lead (IV)-acetate; acetic acid anhydride; acetic acid
4: palladium/charcoal / 350 °C
View Scheme
参考文献
Newman
Journal of the American Chemical Society, 1940 , vol. 62, p. 1683,1686
反应条件
1: amalgamated aluminium; ethanol; benzene / Erhitzen des Reaktionsprodukts in Eisessig
2: xylene
3: lead (IV)-acetate; acetic acid anhydride; acetic acid
View Scheme
参考文献
Newman
Journal of the American Chemical Society, 1940 , vol. 62, p. 1683,1686
反应条件
1: palladium/charcoal / 300 - 320 °C
2: water; ammonium sulfite; ammonia / 160 °C
3: aqueous HBr / Diazotization.Versetzen der Diazoniumsalz-Loesung mit Hg(NO3)2 und KBr in Wasser und Erhitzen des gebildeten Diazonium-tetrabromomercurats(II) mit KBr
View Scheme
参考文献
Ruzicka; Moergeli
Helvetica Chimica Acta, 1936 , vol. 19, p. 377,383
