6-甲基-7-氧杂双环[4.1.0]庚烷-2-酮合成路线 (共 22 条)
反应条件
sodium hydroxide; dihydrogen peroxide; 1-(n-butyl)-3-methylimidazolium triflate in water T=25°C; 0.0833333 h;
参考文献
Bortolini, Olga; Campestrini, Sandro; Conte, Valeria; Fantin, Giancarlo; Fogagnolo, Marco; Maietti, Silvia
European Journal of Organic Chemistry, 2003 , # 24 p. 4804 - 4809
反应条件
1: With copper acetylacetonate; oxygen in ethanol T=20°C; 5 h; Irradiation; 2: With sodium hydroxide in diethyl ether; water 1 h;
参考文献
Barnier; Morisson; Blanco
Synthetic Communications, 2001 , vol. 31, # 3 p. 349 - 357
反应条件
dihydrogen peroxide in water; acetonitrile T=69.84°C; 5 h;
参考文献
Tang, Bo; Dai, Weili; Sun, Xiaoming; Guan, Naijia; Li, Landong; Hunger, Michael
Green Chemistry, 2014 , vol. 16, # 4 p. 2281 - 2291
反应条件
pyridine; oxygen in hexane 0.166667 h; UV-irradiation; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Clennan, Edward L.; Zhang, Dong; Singleton, Jamie
Photochemistry and Photobiology, 2006 , vol. 82, # 5 p. 1226 - 1232
反应条件
silica gel; lithium iodide 0.5 h; Ambient temperature;
参考文献
Kotsuki, Hiyoshizo; Shimanouchi, Tomoyasu; Ohshima, Reiji; Fujiwara, Shunsuke
Tetrahedron, 1998 , vol. 54, # 12 p. 2709 - 2722
反应条件
KNO2; Aliquatreg; 336 in 1,4-dioxane Heating; Title compound not separated from byproducts;
参考文献
Kasum, Bruno; Prager, Rolf H.
Australian Journal of Chemistry, 1990 , vol. 43, # 1 p. 63 - 68
反应条件
(R)-CSA; dihydrogen peroxide in diethyl ether T=20°C;
参考文献
Chemistry - A European Journal, , vol. 14, # 23 p. 6849 - 6851
反应条件
1: 49 percent / HCl / 0 °C 2: H2/PtO2 / methanol 3: diethyl peroxide, Ph3P / 220 °C / 5 Torr / other methylcyclohexanol cis-diols View Scheme
参考文献
Robinson, Philip L.; Evans, Slayton A.
Journal of Organic Chemistry, 1985 , vol. 50, # 20 p. 3860 - 3863
反应条件
1,3,5-tri-t-butylbenzene; H-mordenite in chlorobenzene Rearrangement; 0.5 h; Heating; Product distribution; Further Variations:Reagents;
参考文献
European Journal of Organic Chemistry, , # 10 p. 1905 - 1911
反应条件
Amberlyst 15; sodium iodide in acetone T=20°C; deoxygenation; 3 h;
参考文献
Righi, Giuliana; Bovicelli, Paolo; Sperandio, Anna
Tetrahedron, 2000 , vol. 56, # 12 p. 1733 - 1737