5-甲基己-1-烯-3-酮合成路线 （共 14 条）
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=0°C;
参考文献
GLAXO GROUP LIMITED
Patent: WO2006/398 A1, 2006 ;
Location in patent: Page/Page column 37 ;
反应条件
oxalyl dichloride; TEA; dimethyl sulfoxide in tetrahydrofuran; dichloromethane T=-60°C; 0.5 h;
参考文献
Hammen; Braisted; Northrup
Synthetic Communications, 1991 , vol. 21, # 21 p. 2157 - 2163
反应条件
1: trans vinyl bromide With magnesium in tetrahydrofuran Reflux; 2: N-methoxy-N,3-dimethylbutanamide in tetrahydrofuran T=20°C; 16 h;
参考文献
Wouters, Felipe C.; Rocha, Daniele F. O.; Goncalves, Caroline C. S.; MacHado, Glauco; Marsaioli, Anita J.
Journal of Natural Products, 2013 , vol. 76, # 9 p. 1559 - 1564
反应条件
in tetrahydrofuran T=0°C; 1 h;
参考文献
Zhao, Zhong; Araldi, Gian Luca; Xiao, Yufang; Reddy, Adulla P.; Liao, Yihua; Karra, Srinivasa; Brugger, Nadia; Fischer, David; Palmer, Elizabeth
Bioorganic and Medicinal Chemistry Letters, 2007 , vol. 17, # 23 p. 6572 - 6575
反应条件
1.1: thionyl chloride; N,N-dimethyl-formamide / 1 h / 20 °C / |Cooling with ice 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: magnesium / tetrahydrofuran / |Reflux 2.2: 16 h / 20 °C View Scheme
参考文献
Wouters, Felipe C.; Rocha, Daniele F. O.; Goncalves, Caroline C. S.; MacHado, Glauco; Marsaioli, Anita J.
Journal of Natural Products, 2013 , vol. 76, # 9 p. 1559 - 1564
反应条件
palladium on activated charcoal; diethyl ether Hydrogenation;
参考文献
Nasarow; Kuwarsina
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 1329
Chem.Abstr., 1949 , p. 2161
反应条件
toluene-4-sulfonic acid Bei der Destillation unter vermindertem Druck;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 556
Chem.Abstr., 1941 , p. 4733
参考文献
Blaise; Maire
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1906 , vol. 142, p. 216
Bulletin de la Societe Chimique de France, 1908 , vol. <4>3, p. 268,270
反应条件
Destillieren unter vermindertem Druck;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 556
Chem.Abstr., 1941 , p. 4733
反应条件
bei der Ozonisierung und folgenden Spaltung mit wss.H2O2;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 556
Chem.Abstr., 1941 , p. 4733
