5-乙基-4,6,11-三氧杂-1-氮杂-5-硅杂双环[3.3.3]十一烷合成路线 （共 9 条）
反应条件
in hexadeuterioacetone Kinetics; byproducts: ClSi(OCH2CH2)3N; not isolated, reaction followed by (1)H-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 296, p. 315 - 320
反应条件
potassium hydroxide in 1,4-dioxane
T=80°C; 1 h;
参考文献
D'yakov, V. M.; Makarov, A. F.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294
反应条件
in chloroform
T=0 - 20°C; Inert atmosphere;
参考文献
Voronkov; Kuznetsova
Russian Journal of General Chemistry, 2009 , vol. 79, # 5 p. 925 - 927
反应条件
in chloroform
T=20°C; 12 h;
参考文献
Voronkov, M. G.; Pestunovich, V. A.; Petukhov, L. P.; Rakhlin, V. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 3 p. 637
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 3 p. 699
反应条件
in xylene
2 h; Heating;
参考文献
Nies, J. Dirk; Bellama, Jon M.; Ben-Zvi, Nava
Journal of Organometallic Chemistry, 1985 , vol. 296, p. 315 - 320
反应条件
T=140 - 150°C; Yields of byproduct given;
参考文献
Voronkov, M. G.; Kuznetsova, G. A.; Baryshok, V. P.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 7 p. 1682,1512 - 1513
反应条件
1: heptafluoroiodopropane / acetonitrile / 0.5 h / 20 °C / Irradiation
2: CH2Cl2 / 12 h / 30 °C
View Scheme
参考文献
Voronkov, M. G.; Baryshok, V. P.; Petukhov, L. P.; Rakhlin, V. I.; Mirskov, R. G.; Pestunovich, V. A.
Journal of Organometallic Chemistry, 1988 , vol. 358, p. 39 - 56
反应条件
1: 15 percent / iodine / CH2Cl2 / -60 °C
2: CH2Cl2 / 12 h / 30 °C
View Scheme
参考文献
Voronkov, M. G.; Baryshok, V. P.; Petukhov, L. P.; Rakhlin, V. I.; Mirskov, R. G.; Pestunovich, V. A.
Journal of Organometallic Chemistry, 1988 , vol. 358, p. 39 - 56
反应条件
potassium hydroxide in xylene
参考文献
Voronkov,M.G.; Zelchan,G.I.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1965 , vol. 1, p. 33 - 37
Khimiya Geterotsiklicheskikh Soedinenii, 1965 , vol. 1, p. 51 - 57
