(R)-(-)-扁桃酸甲酯合成路线 (共 107 条)
反应条件
5 Pt/Al2O3; hydrogen; acetic acid in toluene T=19.84°C; P=30003 Torr;
参考文献
Catalysis Letters, , vol. 141, # 11 p. 1616 - 1620
反应条件
hydrogen; acetic acid T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
boron trifluoride diethyl etherate; mercury(II) trifluoroacetate
参考文献
Aggarwal, Varinder K.; Thomas, Abraham; Schade, Steffen
Tetrahedron, 1997 , vol. 53, # 48 p. 16213 - 16228
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
anhydrous magnesium perchlorate in acetonitrile 240 h; dark; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 108, p. 1989
反应条件
benzoyl-formic acid methyl ester; anhydrous magnesium perchlorate in acetonitrile-D3 T=-25 - 0°C; 1 h; Yield given. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 54, # 6 p. 1313 - 1320
反应条件
Pseudomonas sp. lipase immobilized in poly(ethylene) oxide in di-isopropyl ether T=25°C; 96 h;
参考文献
Tetrahedron Letters, , vol. 43, # 30 p. 5225 - 5227
反应条件
1.1: KDA / tetrahydrofuran / 1 h / -110 °C 1.2: 91 percent / tetrahydrofuran / 0.25 h / -110 °C 2.1: t-BuOK / tetrahydrofuran / 0.25 h / 0 °C 3.1: α-AD-mix; (DHQ)2PHAL; methanesulfonamide / H2O; 2-methyl-propan-2-ol / 0 °C 3.2: sodium sulfite; H2O / 2-methyl-propan-2-ol / 0.75 h / 0 - 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 5, # 8 p. 2270 - 2280
反应条件
5 Pt/Al2O3; hydrogen; acetic acid in toluene T=19.84°C; P=30003 Torr;
参考文献
Catalysis Letters, , vol. 141, # 11 p. 1616 - 1620