2,8-二甲基-5-壬酮合成路线 （共 13 条）
反应条件
hydrogenchloride; sodium borohydride in methanol; hexane; ethyl acetate
参考文献
Abbott Laboratories
Patent: US5142056 A1, 1992 ;
US 5142056 A
反应条件
Reduktion nach Kishner;
参考文献
Petrow; Rosslowa
Zhurnal Obshchei Khimii, 1940 , vol. 10, p. 974
Chem. Zentralbl., 1941 , vol. 112, # I p. 886
反应条件
diethyl ether
T=-60°C;
参考文献
Bartlett et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 1771
反应条件
1: BuLi / tetrahydrofuran / 1.) -78 deg C, 5 min, 2.) -78 deg C, 4 h
2: tetrahydrofuran; diethyl ether / 1.) -78 to 20 deg C, 2.) reflux, 10 h
3: 2 N aq. HCl / tetrahydrofuran; diethyl ether / 10 h / 20 °C
View Scheme
参考文献
Katritzky, Alan R.; Zhang, Guifen; Jiang, Jinlong
Journal of Organic Chemistry, 1995 , vol. 60, # 23 p. 7605 - 7611
反应条件
iron(III) oxide
T=450 - 490°C;
参考文献
Mailhe
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1913 , vol. 157, p. 221
Bulletin de la Societe Chimique de France, 1914 , vol. <4> 15, p. 325
反应条件
aluminium trichloride
T=0 - 5°C;
参考文献
Antares Trust Registered
Patent: US1995752 , 1933 ;
参考文献
Ryu, Ilhyong; Ryang, Membo; Rhee, Ilsong; Omura, Haruo; Murai, Shinji; Sonoda, Noboru
Synthetic Communications, 1984 , vol. 14, # 12 p. 1175 - 1180
参考文献
Petrow; Rosslowa
Zhurnal Obshchei Khimii, 1940 , vol. 10, p. 974
Chem. Zentralbl., 1941 , vol. 112, # I p. 886
参考文献
Petrow; Rosslowa
Zhurnal Obshchei Khimii, 1940 , vol. 10, p. 974
Chem. Zentralbl., 1941 , vol. 112, # I p. 886
反应条件
T=-60°C; und anschliessend mit CO2;
参考文献
Bartlett et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 1771
