DL-β-乙基苯乙基乙醇合成路线 （共 26 条）
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Farmaco, Edizione Scientifica, , vol. 12, p. 836,844
Anales de la Real Sociedad Espanola de Fisica y Quimica, , vol. <B> 54, p. 505,509
Journal of the American Chemical Society, , vol. 77, p. 369,371
反应条件
triethylsilane; indium tribromide; sulfuric acid in chloroform T=20°C; 20 h;
参考文献
Sakai, Norio; Usui, Yuta; Ikeda, Reiko; Konakahara, Takeo
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3397 - 3401
反应条件
1,4-dioxane; copper oxide-chromium oxide T=250°C; P=147102 - 220652 Torr; Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 56, p. 2419,2422
反应条件
1: With [CpFe(CO)2(PCy3)][BF4]; phenyl silane T=100°C; 48 h; IrradiationNeat (no solvent)Inert atmosphere; 2: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
Bezier, David; Venkanna, Gopaladasu T.; Castro, Luis C. Misal; Zheng, Jianxia; Roisnel, Thierry; Sortais, Jean-Baptiste; Darcel, Christophe
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 10 p. 1879 - 1884
反应条件
1: With [RhCl(η2:η2-cycloocta-1,5-diene)]2; N,N,N',N'-tetramethyl-1,4-butanediamine in acetonitrile P=10351 Torr; Autoclave; 2: With hydrogen in acetonitrile T=60°C; P=10351 Torr; 21 h; Autoclave;
参考文献
Cheung, Lawrence L. W.; Vasapollo, Giuseppe; Alper, Howard
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 10 p. 2019 - 2022
反应条件
tri-ruthenium(0)dodecacarbonyl; 2-(dicyclohexylphosphino)-1-methyl-1H-imidazole; water; hydrogen; lithium chloride in 1-methyl-pyrrolidin-2-one T=130°C; P=60 Torr; 20 h; Autoclave; regioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 10 p. 2949 - 2953
反应条件
[Ru(η4-COD)(η3-methylallyl)2]; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-imidazole; hydrogen in toluene T=160°C; P=37503.8 Torr; 24 h; AutoclaveInert atmosphere; Overall yield = 88 percentChromat.; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 135, # 38 p. 14306 - 14312
反应条件
in pentane T=35°C; 4 h;
参考文献
Boireau, G.; Abenhaim, D.; Henry-Basch, E.
Tetrahedron, 1980 , vol. 36, p. 3061 - 3070
反应条件
triphenylphosphine in toluene T=0°C; 3 h;
参考文献
European Journal of Organic Chemistry, , # 23 p. 4445 - 4450
反应条件
1: With chloro-trimethyl-silane in tetrachloromethane T=20°C; 2.5 h; 2: With 4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran T=0°C; Wittig rearrangement; 1 h;
参考文献
Tetrahedron, , vol. 62, # 42 p. 9832 - 9839
