1,4-二甲基-2,5-二苯基苯合成路线 （共 15 条）
参考文献
Hadizad, Tayebeh; Zhang, Jidong; Zhi, Yuan Wang; Gorjanc, Timothy C.; Py, Christophe
Organic Letters, 2005 , vol. 7, # 5 p. 795 - 797
反应条件
sodium hydroxide in water 1 h; Reflux;
参考文献
Khalafi-Nezhad, Ali; Panahi, Farhad
Journal of Organometallic Chemistry, 2012 , vol. 717, p. 141 - 146
反应条件
Pd-PEPPSI-IPent in tetrahydrofuran; anhydrous butyl ether; toluene T=40°C;
参考文献
Hornillos, Valentin; Giannerini, Massimo; Vila, Carlos; Fananas-Mastral, Martin; Feringa, Ben L.
Organic Letters, 2013 , vol. 15, # 19 p. 5114 - 5117
反应条件
PdCl2(PPh2(CH2)4PPh2) in tetrahydrofuran 16 h; Heating;
参考文献
Kelley, Charles J.; Ghiorghis, Alem; Kauffman, Joel M.
Journal of Chemical Research, Miniprint, 1997 , # 12 p. 2701 - 2733
反应条件
1: 74 percent / conc. H2SO4, H5IO6, I2, glacial HOAc / H2O / 3 h / 70 °C 2: 1) Mg / 2) NiCl2(PPh3)2 / 1) Et2O, 2h, reflux, 2) Et2O, 16h, reflux View Scheme
参考文献
Deuschel
Helvetica Chimica Acta, 1951 , vol. 34, p. 2403,2410
反应条件
1: n-butyllithium / tetrahydrofuran / -78 - -40 °C 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 18 h / Reflux View Scheme
参考文献
Pham, Van Chung; Huh, Geun; Kim, Jungahn; Choo, Dong Joon; Lee, Jae Yeol
Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 5 p. 1781 - 1783
反应条件
magnesium; NiCl2((PPh3)P)2 1) Et2O, 2h, reflux, 2) Et2O, 16h, reflux; Yield given. Multistep reaction;
参考文献
Platt, Karl L.; Setiabudi, Frans
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 15 p. 2005 - 2010
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran Suzuki coupling; 18 h; Reflux;
参考文献
Pham, Van Chung; Huh, Geun; Kim, Jungahn; Choo, Dong Joon; Lee, Jae Yeol
Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 5 p. 1781 - 1783
反应条件
palladium on activated charcoal
参考文献
Deuschel
Helvetica Chimica Acta, 1951 , vol. 34, p. 2403,2410
反应条件
1: NBS, benzoylperoxide / CCl4 / 3 h / Heating 2: acetic acid / 22 h / Heating 3: 87 percent / 15percent NaOH / methanol / 6 h / 50 °C 4: 48 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature 5: 1) PhLi / 1) THF, benzene, Et2O, -70 deg C, 2a) THF, -50 deg C, 2 h, 2b) -50 to -10 deg C, 1 h 6: 64 percent / benzene / 144 h / Irradiation 7: 75 percent / DDQ / benzene / 48 h / Heating View Scheme
参考文献
Platt, Karl L.; Setiabudi, Frans
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 15 p. 2005 - 2010
