1-(三甲基硅氧基)环戊烯合成路线 （共 155 条）
反应条件
1.1: 39 percent / titanium tetrachloride / CH2Cl2 / 2 h / -45 °C 2.1: NaH / dimethylformamide / 3 h / 20 °C 2.2: 71 percent / dimethylformamide / 12 h / 20 °C 3.1: 92 percent / NaBH4 / ethanol / 1 h / 0 °C 4.1: 86 percent / PPh3; DIAD / tetrahydrofuran / 20 °C View Scheme
参考文献
Bunnage, Mark E.; Davies, Stephen G.; Parkin, Richard M.; Roberts, Paul M.; Smith, Andrew D.; Withey, Jonathan M.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 22 p. 3337 - 3354
反应条件
tert.-butylhydroperoxide; titanium silicate 24 h; Heating;
参考文献
Chemical Communications, , # 16 p. 1969 - 1970
反应条件
fluorine in various solvent(s) T=-78°C; 3.5 h;
参考文献
Purrington, Suzane T.; Lazaridis, Nicholas V.; Bumgardner, Carl L.
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2715 - 2716
反应条件
BnNMe3(+)F(-) in tetrahydrofuran 16 h; Ambient temperature;
参考文献
Hirsch, Elisabeth; Huenig, Siegfried; Reissig, Hans-Ulrich
Chemische Berichte, 1982 , vol. 115, # 12 p. 3687 - 3696
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 16 h; Ambient temperature;
参考文献
Hirsch, Elisabeth; Huenig, Siegfried; Reissig, Hans-Ulrich
Chemische Berichte, 1982 , vol. 115, # 12 p. 3687 - 3696
反应条件
[VO(OEt)Cl2] in dichloromethane 1) -75 deg C, 3 h, 2) -30 deg C, 4 h;
参考文献
Fujii Takashi; Hirao, Toshikazu; Ohshiro, Yoshiki
Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5823 - 5826
反应条件
oxygen; palladium matal-containing silica-supported catalyst in various solvent(s) T=59.9°C; 24 h; Pd(0) supported on various zeolites , influence of calcination and reaction temperature and of the solvent; Product distributionMechanism;
参考文献
Baba, Toshide; Nakano, Kaichiro; Nishiyama, Satoru; Tsuruya, Shigeru; Masai, Mitsuo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1990 , # 7 p. 1113 - 1119
反应条件
tris(cetyl)pyridinium 12-tungstophosphate; dihydrogen peroxide in dichloromethane T=20°C; 9 h;
参考文献
Journal of Organic Chemistry, , vol. 62, # 21 p. 7174 - 7177
反应条件
antimony trichloride in dichloromethane T=0°C; 1 h;
参考文献
Journal of Organic Chemistry, , vol. 47, # 26 p. 5099 - 5102
反应条件
[Pd(1,2-bis(diphenylphosphino)ethane)(OAc)2] in acetonitrile T=80°C; var. catalyst, solvent;; Product distribution;
参考文献
Chemistry Letters, , p. 1133 - 1136
