1-苯基茚; 1-苯基-1H-茚合成路线 （共 29 条）
反应条件
piperidine; triphenylphosphine; palladium dichloride in water; acetone
T=20°C; 45 h; Inert atmosphere;
参考文献
Rosocha, Gregory; Batey, Robert A.
Tetrahedron, 2013 , vol. 69, # 41 p. 8758 - 8768
反应条件
toluene-4-sulfonic acid; acetic acid
参考文献
Millerr,L.L.; Boyer,R.F.
Journal of the American Chemical Society, 1971 , vol. 93, # 3 p. 650 - 656
反应条件
TpRuPPh3(MeCN)2SbF6 in toluene
T=105°C; 36 h;
参考文献
Odedra, Arjan; Datta, Swarup; Liu, Rai-Shung
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3289 - 3292
反应条件
sulfuric acid; phenyllithium in water; acetic acid; toluene
参考文献
Sterling Winthrop Inc.
Patent: US5569655 A1, 1996 ;
反应条件
1: in diethyl ether
T=-78 - 20°C;
2: With toluene-4-sulfonic acid in toluene
1.5 h;
参考文献
Resconi, Luigi; Camurati, Isabella; Grandini, Cristiano; Rinaldi, Marilisa; Mascellani, Nicoletta; Traverso, Orazio
Journal of Organometallic Chemistry, 2002 , vol. 664, # 1-2 p. 5 - 26
反应条件
dichloro(2-pyridinecarboxylato)gold in dichloromethane
T=0°C; 1 h;
参考文献
McGonigal, Paul R.; De Leon, Claudia; Wang, Yahui; Homs, Anna; Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13093 - 13096
反应条件
1: 92 percent / K2CO3; MeOH / CH2Cl2 / 2 h / 25 °C
2: 62 percent / TpRuPPh3(MeCN)2SbF6 / toluene / 36 h / 105 °C
View Scheme
参考文献
Odedra, Arjan; Datta, Swarup; Liu, Rai-Shung
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3289 - 3292
反应条件
1: 85 percent / CuI; P(t-Bu)3; diisopropylamine / Pd(PhCN)2Cl2 / toluene / 10 h / 20 °C
2: 92 percent / K2CO3; MeOH / CH2Cl2 / 2 h / 25 °C
3: 62 percent / TpRuPPh3(MeCN)2SbF6 / toluene / 36 h / 105 °C
View Scheme
参考文献
Odedra, Arjan; Datta, Swarup; Liu, Rai-Shung
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3289 - 3292
反应条件
1: 65 percent / FeCl3 / 12 h / 100 °C
2: 85 percent / CuI; P(t-Bu)3; diisopropylamine / Pd(PhCN)2Cl2 / toluene / 10 h / 20 °C
3: 92 percent / K2CO3; MeOH / CH2Cl2 / 2 h / 25 °C
4: 62 percent / TpRuPPh3(MeCN)2SbF6 / toluene / 36 h / 105 °C
View Scheme
参考文献
Odedra, Arjan; Datta, Swarup; Liu, Rai-Shung
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3289 - 3292
反应条件
bis-(trifluoromethylsulphonyl)amine; platinum (II) chloride in 1,2-dichloro-ethane
T=80°C; 10 h;
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
