1-硝基-4-苯基乙炔苯合成路线 （共 107 条）
反应条件
1: AlCl3
2: PCl5 / 1 h
3: NaOMe / methanol
View Scheme
参考文献
Youssef,A.-H.A.; Abdel-Rehiem,A.G.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1976 , vol. 14, p. 101 - 105
反应条件
1: AlCl3
2: PCl5 / 1 h
3: NaOMe / methanol
View Scheme
参考文献
Youssef,A.-H.A.; Abdel-Rehiem,A.G.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1976 , vol. 14, p. 101 - 105
反应条件
1: SPHOS; tris-(dibenzylideneacetone)dipalladium(0); tetra-n-butylammonium fluoride trihydrate / 1-methyl-pyrrolidin-2-one; water / 4 h / 50 °C
2: 1-methyl-pyrrolidin-2-one / 14 h / 80 °C
View Scheme
参考文献
Tartaggia, Stefano; De Lucchi, Ottorino; Goossen, Lukas J.
European Journal of Organic Chemistry, 2012 , # 7 p. 1431 - 1438
反应条件
air; potassium tert-butylate in N,N-dimethyl-formamide
1.5 h; Ambient temperature;
参考文献
Akiyama, Shuzo; Tajima, Kunihiko; Nakatsuji, Shin'ichi; Nakashima, Kenichiro; Abiru, Kazuko; Watanabe, Miwa
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 7 p. 2043 - 2052
反应条件
sodium hydroxide in ethanol
T=60°C; 20 h;
参考文献
Orlov; Sokovikov; Kotov; Starikov
Russian Journal of Organic Chemistry, 2000 , vol. 36, # 12 p. 1735 - 1738
反应条件
palladium diacetate; potassium carbonate; triphenylphosphine in ethanol
T=70°C; 24 h;
参考文献
Barros, Jose C.; Souza, Andrea L. F.; Da Silva, Joaquim F. M.; Antunes
Catalysis Letters, 2011 , vol. 141, # 4 p. 549 - 553
反应条件
1,4-dioxane; potassium hydroxide
参考文献
Dombrowskii; Jurkewitsch; Terent'ew
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 3047,3049
J. Gen. Chem. USSR (Engl. Transl.), 1957 , vol. 27, p. 3077
反应条件
bis(η3-allyl-μ-chloropalladium(II)) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 0.5 h;
参考文献
Bumagin, N. A.; Bumagina, I. G.; Kashin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1981 , vol. 261, p. 532 - 535
Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 261, # 5 p. 1141 - 1144
反应条件
in 1,2-dichloro-ethane
T=120 - 130°C; 1.5 h;
参考文献
Kashin, N. A.; Bumagina, I. G.; Bumagin, N. A.; Beletskaya, I. P.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # 1 p. 18 - 24
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 1 p. 21 - 28
反应条件
N,N-dimethyl acetamide; tetrabutyl-ammonium chloride; sodium carbonate
T=25°C; 24 h; Inert atmosphere;
参考文献
Jones, Roderick C.; Canty, Allan J.; Caradoc-Davies, Tom; Davies, Noel W.; Gardiner, Michael G.; Marriott, Philip J.; Ruehle, Christian P. G.; Tolhurst, Vicki-Anne
Dalton Transactions, 2010 , vol. 39, # 16 p. 3799 - 3801
