9-(4-甲基苯基)-9H-咔唑合成路线 （共 25 条）
反应条件
potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine in toluene T=110°C; 12 h; Inert atmosphere;
参考文献
Rajakumar, Perumal; Venkatesan, Nagarathinam; Sekar, Karuppannan; Nagaraj, Subramani; Rengasamy, Ramasamy
Australian Journal of Chemistry, 2014 , vol. 67, # 4 p. 636 - 643
反应条件
cBRIDP; bis(η3-allyl-μ-chloropalladium(II)); methyl-magnesium chloride in tetrahydrofuran; anhydrous xylene T=5°C; Buchwald-Hartwig Coupling; Inert atmosphereReflux; Reagent/catalystTime;
参考文献
TAKASAGO INTERNATIONAL CORPORATION; NAKAYAMA, Yuji; KOBAYASHI, Tohru
Patent: WO2013/32035 A1, 2013 ;
Location in patent: Page/Page column 30; 31 ;
反应条件
copper(l) iodide; 1-Hydroxymethyl-1H-benzotriazole; potassium tert-butylate in dimethyl sulfoxide T=120°C; 18 h; Inert atmosphere;
参考文献
Jha, Rajeev R.; Singh, Jaspal; Tiwari, Rakesh K.; Verma, Akhilesh K.
Arkivoc, 2012 , vol. 2013, # 2 p. 228 - 248
反应条件
potassium carbonate; 18-crown-6 ether in methanol
参考文献
Nakaya, Tadao; Yamauchi, Takao; Tajima, Akio; Mouri, Hidemasa
Patent: US2003/23099 A1, 2003 ;
反应条件
copper(l) iodide; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in toluene T=140°C; 48 h; Inert atmosphereSealed tube;
参考文献
Liao, Qian; Zhang, Liyun; Wang, Fei; Li, Shutao; Xi, Chanjuan
European Journal of Organic Chemistry, 2010 , # 28 p. 5426 - 5431
反应条件
tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; Verkade nonionic superbase in toluene T=80°C; 24 h; Inert atmosphere;
参考文献
Zhou, Yibo; Verkade, John G.
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 4 p. 616 - 620
反应条件
tBu2P-N=P(iBuPCH2CH2)3N; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate in toluene T=100°C; 24 h; Inert atmosphere;
参考文献
Zhou, Yibo; Verkade, John G.
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 4 p. 616 - 620
反应条件
potassium carbonate in 1,2-diisopropylbenzene
参考文献
Takasago International Corporation
Patent: US5736284 A1, 1998 ;
反应条件
copper diacetate; sodium carbonate; ethylene glycol in isopropyl alcohol T=85°C; Ullmann Condensation; 16 h; Inert atmosphere; Catalytic behavior; Reagent/catalyst;
参考文献
Zhu, Daqian; Liu, Qi; Luo, Bingling; Chen, Meihui; Pi, Rongbiao; Huang, Peng; Wen, Shijun
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 11-12 p. 2172 - 2178
反应条件
copper diacetate; sodium carbonate in isopropyl alcohol T=85°C; Ullmann Condensation; 16 h; Inert atmosphere;
参考文献
Zhu, Daqian; Liu, Qi; Luo, Bingling; Chen, Meihui; Pi, Rongbiao; Huang, Peng; Wen, Shijun
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 11-12 p. 2172 - 2178
