1: RuCl2(PCy3)2(3-phenyl-1H-inden-1-ylidene) / benzene / 2 h / 40 °C / Inert atmosphere 2: tert.-butylhydroperoxide; RuCl2(PCy3)2(3-phenyl-1H-inden-1-ylidene) / decane; benzene / 40 °C / Inert atmosphere View Scheme

1: RuCl2(PCy3)2(3-phenyl-1H-inden-1-ylidene) / benzene / 2 h / 40 °C / Inert atmosphere 2: decane; ethyl acetate / 72 h / 40 °C / Inert atmosphere View Scheme

oxygen in dimethyl sulfoxide T=20°C; P=1500.15 Torr; pH=6; 24 h; aq. bufferEnzymatic reaction; regioselective reaction;

1: 78 percent / [1,3-dimesitylimidazolidin-2-yl]Cl2(PCy3)Ru=CHPh; vinyloxytrimethylsilane / toluene / 2 h / Heating 2: aq. HCl View Scheme

C57H48Cl2F9N2PRu in dichloromethane T=20°C; 0.5 h; Inert atmosphere;