1,2-二乙氧基-1,1,2,2-四甲基二硅烷合成路线 （共 13 条）
反应条件
triethylamine in dichloromethane T=0°C; 1 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
反应条件
potassium cyanide Heating;
参考文献
Kumada,M.; Ishikawa,M.
Journal of Organometallic Chemistry, 1964 , vol. 1, p. 411 - 419
参考文献
Kumada et al.
Journal of Organic Chemistry, 1956 , vol. 21, p. 1264,1267
参考文献
Kumada et al.
Journal of Organic Chemistry, 1956 , vol. 21, p. 1264,1267
反应条件
1: 4-bromo-benzoic acid ethyl ester With N-ethyl-N,N-diisopropylamine; palladium dichloride; biphenyl-2-yl-di-tert-butyl-phosphane in 1-methyl-pyrrolidin-2-one T=60°C; 0.166667 h; 2: 1,2-diethoxy-1,1,2,2-tetramethyldisilane in dichloromethane T=60°C; 10 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
反应条件
1: 4-bromo-benzoic acid ethyl ester With N-ethyl-N,N-diisopropylamine; palladium dichloride; biphenyl-2-yl-di-tert-butyl-phosphane in 1-methyl-pyrrolidin-2-one T=60°C; 0.166667 h; 2: 1,2-diethoxy-1,1,2,2-tetramethyldisilane in dichloromethane T=60°C; 10 h;
参考文献
Organic Letters, , vol. 5, # 19 p. 3483 - 3486
反应条件
1: para-iodoanisole With N-ethyl-N,N-diisopropylamine; palladium dichloride; biphenyl-2-yl-di-tert-butyl-phosphane in 1-methyl-pyrrolidin-2-one T=20°C; 0.5 h; 2: 1,2-diethoxy-1,1,2,2-tetramethyldisilane in dichloromethane T=20°C; 48 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
反应条件
1: 1-bromo-4-methoxy-benzene With N-ethyl-N,N-diisopropylamine; palladium dichloride; biphenyl-2-yl-di-tert-butyl-phosphane in 1-methyl-pyrrolidin-2-one T=20°C; 0.166667 h; 2: 1,2-diethoxy-1,1,2,2-tetramethyldisilane in dichloromethane T=60°C; 10 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
参考文献
Kumada et al.
Journal of Organic Chemistry, 1956 , vol. 21, p. 1264,1267
反应条件
meta-chloroperoxybenzoic acid in benzene T=25°C; ΔH(excit.), ΔG(excit.), ΔS(excit.); Rate constantThermodynamic dataMechanism;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 59, # 1.2 p. 151 - 157,130 - 135
