1: With methyllithium in diethyl ether T=0 - 20°C; 2: With bromine in diethyl ether; dichloromethane T=-70°C; 0.75 h;
参考文献
Fox, Mark A.; Cameron, Audrey M.; Low, Paul J.; Paterson, Michael A.J.; Batsanov, Andrei S.; Goeta, Andres E.; Rankin, David W.H.; Robertson, Heather E.; Schirlin, Julien T.
Dalton Transactions, 2006 , # 29 p. 3544 - 3560
1: trimethylsilylacetylene With n-butyllithium in tetrahydrofuran; hexane T=-90°C; 0.5 h; 2: dibromo-difluoro-methane in tetrahydrofuran; hexane T=-110 - -50°C; 1 h; Title compound not separated from byproducts;
1: With 1-bromo-butane; magnesium in diethyl ether T=20°C; 18 h; 2: With bromine in diethyl ether T=-45 - 20°C;
参考文献
Fox, Mark A.; Cameron, Audrey M.; Low, Paul J.; Paterson, Michael A.J.; Batsanov, Andrei S.; Goeta, Andres E.; Rankin, David W.H.; Robertson, Heather E.; Schirlin, Julien T.
Dalton Transactions, 2006 , # 29 p. 3544 - 3560
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -80 °C 1.2: 0.5 h / 0 °C 1.3: 16 h / 20 °C 2.1: [PhCW{OSi(OtBu)3}3] / toluene / 2 h / 20 °C / Molecular sieve View Scheme
参考文献
Lysenko, Sergej; Volbeda, Jeroen; Jones, Peter G.; Tamm, Matthias
Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6757 - 6761
