1-环己烯-1-基(三甲基)硅烷合成路线 （共 20 条）
反应条件
isopentyl nitrite in hydrogenchloride; acetic acid
参考文献
Mallya, M. Narendra; Nagendrappa, Gopalpur; Shashidhara Prasad; Sridhar; Lokanath; Begum
Tetrahedron Letters, 2001 , vol. 42, # 13 p. 2565 - 2568
反应条件
tetramethylene sulfide; anhydrous lithium acetate; iodine in chloroform T=18°C; 24 h; protected from light;
参考文献
Grayson, Elizabeth J.; Witham, Gordon H.
Tetrahedron, 1988 , vol. 44, # 13 p. 4087 - 4094
反应条件
1: AlCl3 / CH2Cl2 / 1 h / Ambient temperature
2: BF3*Et2O / benzene / Heating
View Scheme
参考文献
Paquette, Leo A.; Fristad, William E.; Dime, David S.; Bailey, Thomas R.
Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3017 - 3028
反应条件
(i) AlCl3, (ii) BF3-Et2O; Multistep reaction;
参考文献
Fristad,W.E. et al.
Tetrahedron Letters, 1979 , p. 1999 - 2002
反应条件
aluminium trichloride in dichloromethane
2 h; Ambient temperature;
参考文献
Paquette, Leo A.; Fristad, William E.; Dime, David S.; Bailey, Thomas R.
Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3017 - 3028
反应条件
1: 70percent perchloric acid, N-chlorosuccinimide / H2O; dioxane / 48 h / Ambient temperature
2: 0.813 g / Corey's reagent / CH2Cl2 / 1.) room temperature, 2.5 h, 2.) reflux, 1 h
View Scheme
参考文献
Berti, Giancarlo; Canedoli, Sergio; Crotti, Paolo; Macchia, Franco
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 6 p. 1183 - 1188
反应条件
1: 83 percent / 49percent peracetic acid, sodium acetate / CH2Cl2 / 0.5 h / 20 °C
2: 2.03 g / conc. sulphuric acid / 0.08 h / 0 °C
3: 0.2 g / sodium hydride / dimethylformamide / 0.25 h
View Scheme
参考文献
Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941
反应条件
peracetic acid; sodium acetate in dichloromethane
T=20°C; 0.5 h;
参考文献
Lambert,J.B.; Wang,G.; Finzel,R.B.
Journal of the American Chemical Society, 1987 , vol. 109, p. 7838
反应条件
ruthenium(II) bisoxazoline; sodium hydrogencarbonate; isobutyraldehyde in dichloromethane
T=20°C; 11 h;
参考文献
Srikanth, Abirami; Nagendrappa, Gopalpur; Chandrasekaran, Srinivasan
Tetrahedron, 2003 , vol. 59, # 39 p. 7761 - 7765
反应条件
3,3-dimethyldioxirane in acetone
Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Adam, Waldemar; Prechtl, Frank; Richter, Markus J.; Smerz, Alexander K.
Tetrahedron Letters, 1995 , vol. 36, # 28 p. 4991 - 4994
