1-环己烯-1-基(三甲基)硅烷合成路线 （共 20 条）
反应条件
1: 83 percent / 49percent peracetic acid, sodium acetate / CH2Cl2 / 0.5 h / 20 °C 2: 92.4 percent / lithium aluminium hydride / diethyl ether / 0.17 h 3: chromium trioxide, pyridine / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941
反应条件
(i) BH3, THF, (ii) aq. H2O2, NaOH; Multistep reaction;
参考文献
de Jesus,M. et al.
Journal of Organometallic Chemistry, 1977 , vol. 132, p. 301 - 320
反应条件
1: 56 percent / 1) singlet oxygen/rose bengal, 2) NaBH4 / methanol / Irradiation; 1) 26h, 2) 1h 2: 97 percent / tetra-n-butylammonium fluoride / acetonitrile / 1 h / Heating View Scheme
参考文献
Fristad, William E.; Bailey, Thomas R.; Paquette, Leo A.
Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3028 - 3037
反应条件
2,6-di-tert-butyl-4-methyl-phenol; oxygen; rose bengal in methanol T=-10°C; 23 h; Irradiation;
参考文献
Tetrahedron Letters, , vol. 33, # 24 p. 3461 - 3464
反应条件
oxygen; 5,15,10,20-tetraphenylporphyrin; titanium(IV) isopropylate in dichloromethane T=-10°C; 20 h; Irradiationreaction with other vinyl silanes;
参考文献
Tetrahedron Letters, , vol. 33, # 24 p. 3461 - 3464
反应条件
AcONO2 in dichloromethane T=-15°C; Nitration; 0.5 h;
参考文献
Patil, Govindagouda S.; Nagendrappa, Gopalpur
Chemical Communications, 1999 , # 12 p. 1079 - 1080
反应条件
iron(III) chloride in pyridine Irradiation;
参考文献
Sato, Tadashi; Tonegawa, Tamotsu; Naoi, Kunio; Murayama, Eigoro
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 1 p. 285 - 286
反应条件
isopentyl nitrite in hydrogenchloride; acetic acid
参考文献
Mallya, M. Narendra; Nagendrappa, Gopalpur; Shashidhara Prasad; Sridhar; Lokanath; Begum
Tetrahedron Letters, 2001 , vol. 42, # 13 p. 2565 - 2568
反应条件
1: 83 percent / 49percent peracetic acid, sodium acetate / CH2Cl2 / 0.5 h / 20 °C 2: 92.4 percent / lithium aluminium hydride / diethyl ether / 0.17 h 3: chromium trioxide, pyridine / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Davis, Anthony P.; Hughes, Gwyneth J.; Lowndes, Peter R.; Robbins, Catherine M.; Thomas, Elizabeth J.; Whitham, Gordon H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1934 - 1941
反应条件
chloro-trimethyl-silane; isopentyl nitrite T=-15°C;
参考文献
Mallya, M. Narendra; Nagendrappa, Gopalpur; Shashidhara Prasad; Sridhar; Lokanath; Begum
Tetrahedron Letters, 2001 , vol. 42, # 13 p. 2565 - 2568
