in acetone; benzene
(N2); an acetone soln. of CPh3BF4 was added to a benzene soln. of the Pd complex, the mixed soln. was left agitating for 6 h; reduced in vol., Et2O was added; elem. anal.;
in n-heptane
byproducts: CO; under Ar or N2, exclusion of light, stirred for 10 min at room temp.; observed by IR, removal of solvent in vac., extn. (toluene), VCl3 sepd. by filtration, soln. evapd. to dryness in vac. at room temp., washed with n-heptane (C2Ph6);
in acetone; benzene
(N2); an acetone soln. of CPh3PF6 was added to a benzene soln. of the Pd complex, the mixed soln. was left agitating for 6 h; reduced in vol., Et2O was added; elem. anal.;
in acetone; benzene
(N2); an acetone soln. of CPh3PF6 was added to a benzene soln. of the Pd complex, the mixed soln. was left agitating for 24 h; reduced in vol., pentane was added; elem. anal.;
neodymium in tetrahydrofuran
T=20°C; other reagents; Product distribution;
参考文献
Markevich, I. N.; Sharaev, O. K.; Tinyakova, E. I.; Dolgoplosk, B. A.
Doklady Chemistry, 1983 , vol. 268, p. 43 - 46
Dokl. Akad. Nauk SSSR Ser. Khim., 1983 , vol. 268, # 4 p. 892 - 896
