1,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷合成路线 （共 8 条）
→
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
反应条件
fluorine T=-120°C; 12 h;
参考文献
Miller,W.T. et al.
Journal of the American Chemical Society, 1964 , vol. 86, p. 51 - 56
→
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
反应条件
in monofluoro-trichloromethane T=-77°C; 8.75 h; Further byproducts given;
参考文献
Miller,W.T. et al.
Journal of the American Chemical Society, 1964 , vol. 86, p. 51 - 56
→
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
反应条件
cobalt(III) fluoride T=230 - 240°C; 2 h;
参考文献
Coe, Paul L.; Sellers, Simon F.; Tatlow, John Colin
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 417 - 440
→
865-71-41,1,1,2,2,3,4,4,5,5,5-十一氟-3-(三氟甲基)戊烷+ 1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
反应条件
T=300 - 320°C; 0.5 h; Further byproducts given;
参考文献
Coe, Paul L.; Sellers, Simon F.; Tatlow, John Colin
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 417 - 440
→
865-71-41,1,1,2,2,3,4,4,5,5,5-十一氟-3-(三氟甲基)戊烷+ 1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
反应条件
T=300 - 320°C; 0.5 h; Product distribution;
参考文献
Coe, Paul L.; Sellers, Simon F.; Tatlow, John Colin
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 417 - 440
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
→
反应条件
chlorine T=271°C; 48 h;
参考文献
Tonelli, Claudio; Tortelli, Vito
Journal of Fluorine Chemistry, 1994 , vol. 67, # 2 p. 125 - 128
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷
→
反应条件
toluene
T=500 - 530°C; 2.2 h;
参考文献
Coe, Paul L.; Sellers, Simon F.; Tatlow, John Colin
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 417 - 440
1735-48-41,1,1,2,2,3,4,5,5,6,6,6-十二氟-3,4-二(三氟甲基)己烷+
→
反应条件
toluene
T=510 - 530°C; 2.2 h;
参考文献
Coe, Paul L.; Sellers, Simon F.; Tatlow, John Colin
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 417 - 440
