反应条件
sodium-potassium alloy; sodium in diethyl ether byproducts: benzyl benzoate; N2-atmosphere; slow addn. of PhCH2OH to excess of Na/K-alloy (molar ratio Na:K=37.9:73) with stirring, stirring for 10 d, slow addn. of PhCOCl to sepd. supernatant, stirring for 1 h; evapn. (reduced pressure), fractional distn.; mixt. with benzoyl benzoate (boiling at 102°C/0.7 Torr) not sepd., detd. by (1)H-, (11)B-NMR and IR spectrosocpy;
参考文献
Smith, Keith; Swaminathan, Kalyanaraman
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 2297 - 2300
