1-环己烯基-苯基-甲酮合成路线 （共 47 条）
反应条件
1: With phenyl silane; oxygen; isopropyl alcohol; Mn(dpm)3 in 1,2-dichloro-ethane T=0 - 25°C; 2: With triethyl phosphite in 1,2-dichloro-ethane
参考文献
Magnus; Payne; Waring; Scott; Lynch
Tetrahedron Letters, 2000 , vol. 41, # 50 p. 9725 - 9730
反应条件
phenyl silane; isopropyl alcohol; Mn(dpm)3 T=23°C;
参考文献
Magnus; Waring; Scott
Tetrahedron Letters, 2000 , vol. 41, # 50 p. 9731 - 9733
反应条件
1: With tributylphosphine in tert-butyl alcohol
T=20°C; Morita-Baylis-Hillman type reaction; 3 h; Inert atmosphere;
2: With N-benzyl-N,N,N-triethylammonium chloride; potassium hydroxide in dichloromethane; water; tert-butyl alcohol
T=20°C; Inert atmosphere;
参考文献
Cran, John W.; Krafft, Marie E.; Seibert, Kimberly A.; Haxell, Thomas F.N.; Wright, James A.; Hirosawa, Chitaru; Abboud, Khalil A.
Tetrahedron, 2011 , vol. 67, # 51 p. 9922 - 9943
反应条件
bis(1,5-cyclooctadiene)nickel (0); para-fluorostyrene; pyphos in tetrahydrofuran
T=23°C; 0.166667 h;
参考文献
Zhang, Yongda; Rovis, Tomislav
Journal of the American Chemical Society, 2004 , vol. 126, # 49 p. 15964 - 15965
反应条件
potassium hydroxide; zinc
T=15 - 20°C; 1) CH2Cl2, 2) MeOH;
参考文献
Shono, Tatsuya; Nishiguchi, Ikuzo; Sasaki, Manji; Ikeda, Haruhiko; Kurita, Makoto
Journal of Organic Chemistry, 1983 , vol. 48, # 15 p. 2503 - 2505
反应条件
palladium(II) catalyst in tetrahydrofuran
T=45 - 50°C; 48 h;
参考文献
Goure; Wright; Davis; Labadie; Stille
Journal of the American Chemical Society, 1984 , vol. 106, # 21 p. 6417 - 6422
反应条件
indium trifluoromethanesulfonate; butan-1-ol in dichloromethane
T=20°C; 3 h; Inert atmosphere;
参考文献
Miura, Katsukiyo; Yamamoto, Kiyomi; Yamanobe, Aya; Ito, Keisuke; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira
Chemistry Letters, 2010 , vol. 39, # 7 p. 766 - 767
反应条件
trifluorormethanesulfonic acid in dichloromethane
16 h; Ambient temperature;
参考文献
Olah, George A.; Wu, An-hsiang
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2531 - 2534
反应条件
magnesium in N,N-dimethyl-formamide
T=-20 - 60°C;
参考文献
Aaziz, Akima; Oudeyer, Sylvain; Leonel, Eric; Paugam, Jean Paul; Nedelec, Jean-Yves
Synthetic Communications, 2007 , vol. 37, # 7 p. 1147 - 1154
反应条件
1.1: 23 percent / Grubbs' 2nd generation catalyst / CH2Cl2 / 12 h / Heating
2.1: tributylphosphine / 2-methyl-propan-2-ol / 20 °C
2.2: 99 percent / potassium hydroxide; benzyltriethylammonium chloride / CH2Cl2; 2-methyl-propan-2-ol; H2O
View Scheme
参考文献
Krafft, Marie E.; Seibert, Kimberly A.; Haxell, Thomas F. N.; Hirosawa, Chitaru
Chemical Communications, 2005 , # 46 p. 5772 - 5774
