(OC-6-11)-六氟-锑酸铯合成路线 （共 25 条）
反应条件
in hydrogen fluoride
aq. HF; excess of hydrofluoric acid, according to: V. L. Kolditz, W. Rehak, Z. Anorg. Allg. Chem. 300 (1959) 322;
参考文献
Beer, W. H. J. de; Heyns, Anton M.; Richter, P. W.; Clark, J. B.
Journal of Solid State Chemistry, 1980 , vol. 33, p. 283 - 288
反应条件
in hydrogen fluoride
HF (liquid); dry air atmosphere; heating (50-70 h); evapn.; Raman spectroscopy;
参考文献
Popov, A. I.; Scharabarin, A. V.; Sukhoverkhov, V. F.; Tchumaevsky, N. A.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 576, p. 242 - 254
反应条件
in hydrogen fluoride
HF (liquid); HF condenced onto reagent at 77 K, alowed to warm to room temp., left for 0.5 h, decanted, repeated several times; volatiles removed (vac., ambient temp.);
参考文献
Mazej, Zoran
European Journal of Inorganic Chemistry, 2005 , # 19 p. 3983 - 3987
反应条件
in hydrogen fluoride
HF (liquid); HF condenced onto reagent at 77 K, alowed to warm to room temp., left for 0.5 h, decanted, repeated several times; volatiles removed (vac., ambient temp.), Raman, XRD;
参考文献
Mazej, Zoran
European Journal of Inorganic Chemistry, 2005 , # 19 p. 3983 - 3987
反应条件
in hydrogen fluoride
HF (liquid); react. (Pt(CO)4)(Sb2F11)2 with CsF in anhyds. HF;
参考文献
Von Ahsen, Britta; Wartchow, Rudolf; Willner, Helge; Jonas, Volker; Aubke, Friedhelm
Inorganic Chemistry, 2000 , vol. 39, # 20 p. 4424 - 4432
反应条件
in sulfur dioxide
exclusion of air and moisture; 1. method: NMR-tube; SO2 and SbF5 alternate condensed to CsPH2F4 at 77 K; melted off; shake at 205 K; 2.method: react. in two leg vessel; 1.method: CsSbF6 pptd.; NMR-spectroscopy; 2.method: pptn. separated; solvent removed; Raman-spectroscopy of residue;
参考文献
Minkwitz, Rolf; Liedtke, Andreas
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989 , vol. 44, # 6 p. 679 - 682
反应条件
in further solvent(s)
exclusion of air and moisture; solvent: SO2ClF; SO2ClF and SbF5 alternate condensed to CsPF6 in an NMR-tube at 77 K;; tube melted off; stored at 77 K; product not isolated; detected by NMR;
参考文献
Minkwitz, Rolf; Liedtke, Andreas
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989 , vol. 44, # 6 p. 679 - 682
反应条件
in sulfur dioxide
exclusion of air and moisture; 1. method: NMR-tube; SO2 and SbF5 alternate condensed to CsPHF5 at 77 K; melted off; shake at 205 K; 2.method: react. in two leg vessel; 1.method: CsSbF6 pptd.; NMR-spectroscopy; 2.method: pptn. separated; solvent removed; Raman-spectroscopy of residue;
参考文献
Minkwitz, Rolf; Liedtke, Andreas
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989 , vol. 44, # 6 p. 679 - 682
反应条件
in neat (no solvent)
CsIF4O2 and NF4SbF6 were placed in flask, HF was condensed in at -78°C, mixt. was stirred for 1 h at room temp., cooled to -78°C,sepd. by filtrtaion, HF was pumped off over several h form -64 to -30°C, residue was decomposed; volatiles products were passed through trap at -78, -95, -112 and -210°C; elem. anal.;
参考文献
Christe, Karl O.; Wilson, Richard D.; Schack, Carl J.
Inorganic Chemistry, 1981 , vol. 20, p. 2104 - 2114
反应条件
in neat (no solvent)
Irradiation (UV/VIS); HF condensed on mixt. of AuF3, SbF5 and CsF in vac. line, tube sealed, irradiated at room temp.; slow cooling to -78°C;
参考文献
Hwang, In-Chul; Seppelt, Konrad
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 4 p. 765 - 769
