in neat (no solvent) NO added to Sb deriv. at -196°C (dry box, vacuum line) and warm slowly to room temp.; volatiles pumped off; detd. by vibrational spectroscopy;
参考文献
Vij; Wilson; Tham; Sheehy; Christe
Journal of the American Chemical Society, 2001 , vol. 123, # 26 p. 6308 - 6313
Drake, Greg W.; Dixon, David A.; Sheehy, Jeffrey A.; Boatz, Jerry A.; Christe, Karl O.
Journal of the American Chemical Society, 1998 , vol. 120, # 33 p. 8392 - 8400
in neat (no solvent) byproducts: HO2NO2; react. in a gas/solid-phase reactor, satg. a He stream with H2O2, flowing over solid NOHSO4, pressure: 1 - 2 Torr, temp.: 298 K, time: 0.075 - 2 s; monitoring by IR spectroscopy;
参考文献
Burkholder, James B.; Hammer, Philip D.; Howard, Carleton J.
Journal of Physical Chemistry, 1987 , vol. 91, # 8 p. 2136 - 2144
in sulfur dioxide under N2; Al-complex and NOSbF6 were reacted in SO2 at -196°C, stirred at room temp. for 1 h; filtered, SO2 was slowly removed, CH2Cl2 was condensed, warmed to -20°C with stirring, filtered; elem. anal.;
参考文献
Decken, Andreas; Jenkins, H. Donald Brooke; Nikiforov, Grigori B.; Passmore, Jack
Dalton Transactions, 2004 , # 16 p. 2496 - 2504
