(±)-2-氯-1-苯基乙醇合成路线 (共 94 条)
反应条件
(Ru2(η5-C5Ph4O)2(H)2(CO)4); potassium tert-butylate in toluene T=80°C; 29 h; Reactivity; Reagent/catalystTime;
参考文献
Journal of the American Chemical Society, , vol. 130, # 41 p. 13508 - 13509
反应条件
1: (R)-(+)-2-chloro-1-phenylethyl alcohol With [Ir(η5-C5Me5)(C6H4-2-CH2NHCH3)(NCCH3)](PF6); potassium tert-butylate in toluene T=20°C; 16 h; Inert atmosphere; 2: (S)-2-chloro-1-phenylethanol in toluene T=20°C; 2 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 15, # 46 p. 12780 - 12790
反应条件
water; chlorine in tert-butyl alcohol T=0°C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 322, # 3 p. 394 - 400
反应条件
perchloric acid; 10-methyl-9,10-dihydroacridine in acetonitrile-D3 T=61.9°C; 110 h; Title compound not separated from byproducts;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 9 p. 3049 - 3051
反应条件
tri-tert-butylaluminum; trifluoroacetic acid in toluene T=60°C; Meerwein-Ponndorf-Verley reduction; 24 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 16, # 36 p. 11012 - 11019
反应条件
Lactobacillus brevis dehydrogenase; NADPH; tris(hydroxymethyl)methylamine hydrochloride; magnesium chloride in water T=30°C; pH=7.5; 24 h; Enzymatic reaction;
参考文献
Chemistry - A European Journal, , vol. 16, # 36 p. 11012 - 11019
反应条件
chromium oxychloride in pyridine; dichloromethane T=-78°C; 1 h; various chromyl reagents; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 105, # 8 p. 2368 - 2378
反应条件
water; chlorine in tert-butyl alcohol T=0°C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 322, # 3 p. 394 - 400
反应条件
in ethanol T=27°C; Rhizopus arrhizus ATCC 24563; Yield given. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 33, # 48 p. 7337 - 7340
反应条件
chromium oxychloride in tetrachloromethane T=-78°C; 1 h; various chromyl reagents; Product distribution;
参考文献
Miyaura, N.; Kochi, J. K.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2368 - 2378