反应条件
hydrogenchloride; tert.-butyl lithium in tetrahydrofuran; pentane byproducts: LiCl, N2, PhC(O)Me; under N2, ferrocene suspn. in THF cooled to 0°C, t-BuLi/pentane added, allowed to warm to ambient temp., stirred for 15 min, cooled to -70°C, α-azidostyrene added, allowed to warm to -10°C; aq. HCl added slowly, allowed to warm to ambient temp., poured into H2O,washed (ether), the H2O layer cooled to 0°C, aq. NaOH added slow ly; after 10 min the ppt. collected, rinsed (H2O), dried, sublimed at 120°C and 0.06 mmHg; elem. anal.;
参考文献
Leusen, Daan van; Hessen, Bart
Organometallics, 2001 , vol. 20, p. 224 - 226
