1,2-双(二苯基膦)乙烷合成路线 （共 132 条）
反应条件
in dichloromethane Kinetics; byproducts: CH2CH(CH3)CH2CH(COCH3)2; N2, room temp.; N2 satd. soln. of complex filled in quartz cell; addn. of Ph2PC2H4PPh2 soln.; various initial concentrations caused various yields; not isolated; followed course by UV spectroscopy;
参考文献
Organometallics, , vol. 8, p. 1756 - 1760
反应条件
byproducts: PH(CH3)(tBu3C6H2);
参考文献
Journal of the American Chemical Society, , vol. 119, # 21 p. 5039 - 5040
反应条件
in toluene byproducts: P(CH3)(C6H2(CH(CH3)2)3)CH2CHCH2; (N2, at 23°C); Pd complex in toluene added to a soln. of Pt complex, a soln. of C2H4(P(C6H5)2)2 added; not isolated, detected by NMR;
参考文献
Organometallics, , vol. 25, # 22 p. 5435 - 5448
反应条件
lithium in tetrahydrofuran Ambient temperature;
参考文献
Brooks, Peter; Craig, Donald C.; Gallagher, Michael J.; Rae, A. David; Sarrof, Adrien
Journal of Organometallic Chemistry, 1987 , vol. 323, p. C1 - C4
反应条件
in dichloromethane the Mo compd. was mixed with the free phosphine (molar ratio 1:1) in CH2Cl2 and allowed to react. for 5 days at room temp.;;
参考文献
Poli, Rinaldo; Owens, Beth E.; Krueger, Steven T.; Rheingold, Arnold L.
Polyhedron, 1992 , vol. 11, p. 2301 - 2312
反应条件
in toluene 7 h; Reflux;
参考文献
Boulos, Leila S.; Ewies, Ewies F.; Fahmy, Amin F. M.
Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 6 p. 726 - 738
反应条件
1: 80 percent / toluene / 4 h / Heating 2: 95 percent / Hydrogen / Raney-Ni / 2.5 h / 20 °C / 41253.3 Torr 3: 5N NaOH / aq. ethanol / 14 h / Heating View Scheme
参考文献
Tetrahedron Letters, , vol. 28, # 12 p. 1259 - 1262
反应条件
in not given chromy. (N2);
参考文献
Aresta, Michele; Quaranta, Eugenio; Treglia, Sonia; Ibers, James A.
Organometallics, 1988 , vol. 7, p. 577 - 583
反应条件
in benzene-d6 dissolved in C6D6; crystals were obtained after several weeks in a sealed tube, NMR;
参考文献
Inorganic Chemistry, , vol. 29, p. 3680 - 3685
反应条件
in methanol addn. of excess of ligand to a soln. of the complex in methanol, warming to 50°C for 45 min; removal of volatiles, extn. of residue with light petroleum, filtn., concg. of filtrate, standing at -15°C;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1213 - 1220
