1,2-双(二苯基膦)乙烷合成路线 （共 132 条）
反应条件
in benzene
40 h; Heating; Yield given;
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
in benzene
24 h; Heating;
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
in tetrahydrofuran; 1,4-dioxane
参考文献
Luft; Gerhard; Trabold; Peter
Patent: US4959498 A1, 1990 ;
参考文献
Hoffmann-La Roche Inc.
Patent: US4532358 A1, 1985 ;
反应条件
2-Chloro-2-methylpropane; lithium
1.) THF, 0 deg C, ultrasound irradiation, 10 min, 2.) THF, 2 h; Yield given. Multistep reaction;
参考文献
Chou, Ta-shue; Tsao, Chung-Huang; Hung, Su Chun
Journal of Organic Chemistry, 1985 , vol. 50, # 22 p. 4329 - 4332
反应条件
palladium diacetate; sodium hydroxide; ethylene dibromide in 1,2-dichloro-ethane
7 h; Heating;
参考文献
Grushin, Vladimir V.
Journal of the American Chemical Society, 1999 , vol. 121, # 24 p. 5831 - 5832
反应条件
in dichloromethane
mixing equimolar amts. of Pt{S2P(OEt)2} and Ph2PCH2CH2PPh2 in CH2Cl2 at 25°C gave in fast reaction {(dpe)Pt{S2P(OEt)2}}(1+) and than slow (dpe)Pt{S2P(O)OEt} and EtS2P(OEt)2; identified by NMR;
参考文献
Colton, R.; Ebner, J.; Hoskins, B.F.
Inorganic Chemistry, 1988 , vol. 27, p. 1993 - 1999
反应条件
in toluene
8 h; Reflux;
参考文献
Boulos, Leila S.; Ewies, Ewies F.; Fahmy, Amin F. M.
Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 6 p. 726 - 738
反应条件
in dichloromethane-d2
byproducts: (C6H5)2PC6H4N(CH3)2; (Ar); not isolated, detected by NMR;
参考文献
Hounjet, Lindsay J.; McDonald, Robert; Ferguson, Michael J.; Cowie, Martin
Inorganic Chemistry, 2011 , vol. 50, # 12 p. 5361 - 5378
反应条件
Zinc chloride in tetrahydrofuran
参考文献
Ortho Pharmaceutical Corporation
Patent: US5541217 A1, 1996 ;
