1-(1-环己烯-1-基)-1-丙酮合成路线 （共 21 条）
反应条件
sodium carbonate
T=-20 - 25°C; 18 h;
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
Fe2(S04)3; sulfuric acid; mercury(II) oxide
参考文献
Favorskaya,I.A.; Auvinen,E.M.
Journal of Organic Chemistry USSR (English Translation), 1965 , vol. 1, p. 478 - 480
Zhurnal Organicheskoi Khimii, 1965 , vol. 1, p. 486 - 489
参考文献
Favorskaya,I.A.; Auvinen,E.M.
Journal of Organic Chemistry USSR (English Translation), 1965 , vol. 1, p. 478 - 480
Zhurnal Organicheskoi Khimii, 1965 , vol. 1, p. 486 - 489
反应条件
aluminium trichloride
1.) CH2Cl2, 0 deg C, 1 h, 2.) -90 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Laguerre, Michel; Grignon-Dubois, Micheline; Dunogues, Jacques
Tetrahedron, 1981 , vol. 37, p. 1161 - 1169
反应条件
diethyl ether
anschliessend mit Wasser und wss. H2SO4;
参考文献
Bergs
Chemische Berichte, 1934 , vol. 67, p. 238,242
参考文献
Dermer; Simpson
Pr. Oklahoma Acad., 1953 , vol. 34, p. 160
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
1: AlCl3 / 45 °C
2: NaBH4 / propan-1-ol / 4 h / 30 - 35 °C
3: p-toluenesulfonic acid / toluene / Heating
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
4: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C
5: SOCl2 / 1 h / Heating
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
